The Rare Earths: Their Occurrence, Chemistry, and TechnologyLevy, Stanley Isaac
Science
The Rare Earths: Their Occurrence, Chemistry, and Technology
Levy, Stanley Isaac
Rare earths
Twin plane _a_ (100). Birefringence moderate, positive; plane of optic
axes perpendicular to _b_, nearly parallel to _a_. Acute bisectrix
inclined to _c_ at angle of 1°-4°. Dispersion feeble, ρ < υ. Brittle.
Hardness 5-5¹⁄₂; sp. gr. 4·9-5·3; conchoidal fracture. Lustre
resinous. Colour, red to brown, yellow, yellowish- and greenish-brown.
Transparent when pure; more often translucent to opaque.
Monazite is with difficulty soluble in acids; before the blowpipe it is
infusible; when moistened with sulphuric acid it colours the flame
greenish-blue.
The mineral often occurs massive, yielding angular fragments, but is
most common in rolled grains. It occurs in the gneiss of the Carolinas
and Georgia, and in sands derived from the gneiss, in Idaho and many of
the Pacific States; in Brazil, at various localities in the provinces of
Minas Geraes, Bahia, Espirito Santo; in Queensland, Australia; in
Madagascar; in Ceylon; near Travancore in India; in the Urals; in
Scandinavia, etc. The deposits of commercial value will be treated more
fully in the next chapter. It is of wide distribution as an accessory
constituent of granites, diorites, and gneisses.
Monazite was first described, under the name Turnerite, by Lévy,[103] in
1823; the specimen was from the collection of the English chemist
Turner, who thought it a variety of sphene (titanite), and was named
after him at the suggestion of the mineralogist Heuland. The specimen
was stated to have been found in Dauphiné, but in spite of considerable
examination of the question, the precise locality is still unknown. The
resemblance between Turnerite and the mineral later described as
monazite (μοναζειν = to be solitary) was pointed out by Dana in 1866,
and confirmed by Pisani, 1877. The name Monazite was first used by
Breithaupt[104] in describing a mineral found by Menge (1826)
accompanying zircon in a granite from Miask in the Urals. Breithaupt
concluded, from the high specific gravity, that the mineral contained a
heavy metallic oxide. It was again described as Mengite by Brooke[105]
in 1831. It was re-discovered by Shephard[106] in South Carolina in
1837, and described by him under the name Edwardsite, a variety from
Connecticut being called Eremite. To Shephard belongs the honour of
having discovered its true nature; after analysis he described it as a
‘Basic Sesquiphosphate of the Protoxide of Cerium,’ giving the formula
(modern notation) 3CeO,2P₂O₅, and finding also zirconia, alumina, and
silica in it (his specimen was probably very impure). Gustav Rose[107]
showed this to be identical with monazite in 1840. In 1846 Wöhler
described, under the name Cryptolite, a variety of tetragonal habit
closely resembling zircon. This occurs at Arendal in Norway, enclosed by
apatite, in the granite; it may be obtained by treatment with dilute
nitric acid, which dissolves the apatite.
[103] _Annals of Philosophy_, 1823, ~21~, 241.
[104] _Schweigg. J._ 1829, ~55~, 30.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account