The Working of Steel: Annealing, Heat Treating and Hardening of Carbon and Alloy SteelColvin, Fred H. (Fred Herbert)
Science
The Working of Steel: Annealing, Heat Treating and Hardening of Carbon and Alloy Steel
Colvin, Fred H. (Fred Herbert)
Steel
[Illustration: FIG. 48.--Slowly cooled high-carbon steel, polished,
etched and viewed at 100 magnifications. The dark grains are pearlite,
separated by white films of iron carbide (cementite). Photograph
by H. S. Rawdon.]
In general it may be said that the previous crystalline structure
of a steel is entirely obliterated when it passes just through the
critical range. At that moment, in fact, the ferrite, cementite or
pearlite which previously existed has lost its identity by everything
going into the solid solution called austenite. If sufficient time
is given, the chemical elements comprising a good steel distribute
themselves uniformly through the mass. If the steel be then cooled,
the austenite breaks up into new crystals of ferrite, cementite
and pearlite; and in general if the temperature has not gone far
above the critical, and cooling is not excessively slow, a very
fine texture will result. This is called "refining" the grain;
or in shop parlance "closing" the grain. However, if the heating
has gone above the critical very far, the austenite crystals start
to grow; a very short time at an extreme temperature will cause
a large grain growth. Subsequent cooling gives a coarse texture,
or an arrangement of ferrite, cementite and pearlite grains which
is greatly coarsened, reflecting the condition of the austenite
crystals from which they were born.
It maybe noted in passing that the coarse crystals of cast metal
cannot generally be refined by heat treatment unless some forging
or rolling has been done in the meantime. Heat treatment alone does
not seem to be able to break up the crystals of an ingot structure.
HARDENING
Steel is hardened by quenching from above the upper critical. Apparently
the quick cooling prevents the normal change back to definite and
sizeable crystals of ferrite and cementite. Hardness is associated
with this suppressed change. If the change is allowed to continue
by a moderate reheating, like a tempering, the hardness decreases.
If a piece of steel could be cooled instantly, doubtless austenite
could be preserved and examined. In the ordinary practice of hardening
steels, the quenching is not so drastic, and the transformation of
austenite back to ferrite and cementite is more or less completely
effected, giving rise to certain transitory forms which are known
as "martensite," "troostite," "sorbite," and finally, pearlite.
Austenite has been defined as a solid solution of cementite (Fe3C)
in gamma iron. It is stable at various temperatures dependent upon
its carbon content, which may be any amount up to the saturated
solution containing 1.7 per cent. Austenite is not nearly as hard
as martensite, owing to its content of the soft gamma iron. Fig.
49 shows austenite to possess the typical appearance of any pure,
crystallized substance.
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