Two wires, one of platina, and one of zinc, each one-eighteenth of an
inch in diameter, placed five-sixteenths of an inch apart, and immersed
to the depth of five-eighths of an inch in acid, consisting of one drop
of oil of vitriol and four ounces of distilled water at a temperature of
about 60 deg. Fahrenheit, and connected at the other ends by a copper wire
eighteen feet long, and one-eighteenth of an inch in thickness, yielded
as much electricity in little more than three seconds of time as a
Leyden battery charged by thirty turns of a very large and powerful
plate electric machine in full action. This quantity, although
sufficient if passed at once through the head of a rat or cat to have
killed it, as by a flash of lightning, was evolved by the mutual action
of so small a portion of the zinc wire and water in contact with it that
the loss of weight by either would be inappreciable; and as to the water
which could be decomposed by that current, it must have been insensible
in quantity, for no trace of hydrogen appeared upon the surface of the
platina during these three seconds. It would appear that 800,000 such
charges of the Leyden battery would be necessary to decompose a single
grain of water; or, if I am right, to equal the quantity of electricity
which is naturally associated with the elements of that grain of water,
endowing them with their mutual chemical affinity.
This theory of the definite evolution and the equivalent definite action
of electricity beautifully harmonises the associated theories of
definite proportions and electro-chemical affinity.
According to it, the equivalent weights of bodies are simply those
quantities of them which contain equal quantities of electricity, or
have naturally equal electric powers, it being the electricity which
_determines_ the equivalent number, _because_ it determines the
combining force. Or, if we adopt the atomic theory or phraseology, then
the atoms of bodies which are equivalent to each other in their ordinary
chemical action have equal quantities of electricity naturally
associated with them. I cannot refrain from recalling here the beautiful
idea put forth, I believe, by Berzelius in his development of his views
of the electro-chemical theory of affinity, that the heat and light
evolved during cases of powerful combination are the consequence of the
electric discharge which is at the moment taking place. The idea is in
perfect accordance with the view I have taken of the quantity of
electricity associated with the particles of matter.
The definite production of electricity in association with its definite
action proves, I think, that the current of electricity in the voltaic
pile is sustained by chemical decomposition, or, rather, by chemical
action, and not by contact only. But here, as elsewhere, I beg to
reserve my opinion as to the real action of contact.
Public-domain text, read in full here on John Shaqi.
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