A century of science in America : $b with special reference to the American Journal of Science, 1818-1918
History
A century of science in America : $b with special reference to the American Journal of Science, 1818-1918
American journal of science; Science -- United States -- History
_Changes in Formulas._—Even before the year 1826, Berzelius displayed
great skill in arriving at many formulas that agree with our present
ones, for example, H_{2}O for water, ZnCl_{2} for zinc chloride,
N_{2}O_{5} for nitric acid (anhydride), CaO for calcium oxide, CO and
CO_{2} for the oxides of carbon, and many others. But at the same period
other authorities, especially Gay-Lussac in France and Gmelin in
Germany, on account of a lack of appreciation for Avogadro’s principle
and for other reasons, such as the use of symbols to represent combining
weights rather than atoms, were using different formulas for some of
these compounds, such as HO, ZnCl and NO_{5}, so that their formulas for
many of the compounds of hydrogen, chlorine, nitrogen and several other
elements differed from those of Berzelius. The employment of different
formulas involved the use of different atomic or combining weights. For
example, with the formula H_{2}O for water the composition by weight
requires the ratio 1 to 16 for the weights of the hydrogen and oxygen
atoms, while with HO the ratio is 1 to 8.
Berzelius attempted to bring about greater uniformity in formulas and
atomic weights by making changes in his table of atomic weights
published in 1826. He practically doubled the relative atomic weights of
hydrogen, chlorine, nitrogen, and of the other elements that gave twice
as many atoms in his formulas as in those of others, and at the same
time he wrote the symbols of these elements with a bar across them to
indicate that they represented double atoms. For example, he wrote:
H̶O ZnC̶l N̶O_{5},
instead of
H_{2}O, ZnCl_{2} N_{2}O_{5}
This appears to have been an unfortunate concession to the views of
others on the part of Berzelius, for the barred symbols were not
generally adopted, partly on account of difficulties in printing, and
the great achievement in theory made by him was lost sight of for a long
period of time.
_The Law of Atomic Heats._—In 1819, Dulong and Petit of France, from
experiments upon the specific heats of a number of solid elementary
substances, came to the conclusion that the atoms of simple substances
have equal capacities for heat, or in other words, that the specific
heats of elements multiplied by their atomic weights give a constant
called the atomic heat. For instance, the specific heats of sulphur,
iron, and gold have been given as 0·2026, 0·110, and 0·0324, while their
atomic weights are about 32, 56, and 197, respectively; hence the atomic
heats obtained by multiplication are 6·483, 6·116, and 6·383.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account