A century of science in America : $b with special reference to the American Journal of Science, 1818-1918
History
A century of science in America : $b with special reference to the American Journal of Science, 1818-1918
American journal of science; Science -- United States -- History
This term “ion” remained in comparative obscurity for more than half a
century, when it was brought into great prominence among chemists by
Arrhenius in connection with the ionic theory.
_Cannizzaro’s Ideas._—Up to about 1869 chaos reigned among the formulas
used by different chemists. Various compound radicals and numerous
type-formulas were employed, dualistic and unitary formulas of several
kinds were in use, but the worst feature of the situation was the fact
that more than one system of atomic weights was in vogue, so that water
might be written
HO, H̶O, or H_{2}0
and similar discrepancies might appear in nearly all formulas containing
elements of different valencies. In 1858, however, an article by the
Italian chemist Cannizzaro appeared in which the outlines of a course in
chemical philosophy were presented. This acquired wide circulation in
the form of a pamphlet at a chemical convention somewhat later, and it
dealt so clearly and ably with Avogadro’s principle, Dulong and Petit’s
law, and other points in connection with formulas that it led to a rapid
and almost universal reform among those who were using unsatisfactory
formulas.
At about this time also the dualistic formulas of Berzelius were
generally abandoned, and hydrogen came to be regarded as the
characteristic element of all acids. For instance, CaO.SO_{3}, called
“sulphate of lime,” came to be written CaSO_{4} and was called “calcium
sulphate,” and while it had been shown as early as 1815 by Davy that
“iodic acid,” I_{2}O_{5}, showed no acid reaction until it was combined
with water, the accumulation of similar facts led to the formulation of
sulphuric acid as H_{2}SO_{4} instead of SO_{3} or H_{2}O.SO_{3}, and
that of other “oxygen acids” in a similar way. As a necessary
consequence of this view of acids, the bases came to be regarded as
compounds of the “hydroxyl” group, OH. Therefore the formula for caustic
soda came to be written NaOH instead of Na_{2}O.H_{2}O, and so on.
_The Periodic System of the Elements._—The periodicity of the elements
in connection with their atomic weights was roughly grasped by Newlands
in England, who announced his “law of octaves” in 1863. This was at the
time when the atomic weights were being modified and their numerical
relations properly shown. The subject was worked out more fully by L.
Meyer in Germany a little later, but it was most clearly and elaborately
presented by the Russian chemist Mendeléeff in 1869.
In order that this subject may be explained to some extent Mendeléeff’s
table is given here, with the addition of the recently discovered
elements and some other modifications.
Public-domain text, read in full here on John Shaqi.
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