A century of science in America : $b with special reference to the American Journal of Science, 1818-1918
History
A century of science in America : $b with special reference to the American Journal of Science, 1818-1918
American journal of science; Science -- United States -- History
Thermochemistry has been developed by a comparatively few men who have
contributed a surprisingly large number of results. Favre and
Silbermann, beginning shortly after 1850, improved the apparatus for
calorimetric determinations, which is called the calorimeter, and
published many results. At about the same time Julius Thomsen, and in
1873 Berthelot, began their remarkable series of publications which
continued until recently. Thomsen’s investigations were published in
1882 in =4= volumes. It is probably safe to say that the greater part of
the data of thermochemistry was obtained by these two investigators. The
bomb calorimeter, an apparatus for determining heat values by direct
combustion, was developed by Berthelot. The recent work of Mixter at
Yale, published in the Journal, and of Richards at Harvard should be
mentioned particularly. Mixter’s work in this field began in 1901 (=12=,
347). Using an improved bomb calorimeter, he has developed a method of
determining the heats of formation of oxides by combustion with sodium
peroxide. By this same method as well as by direct combustion in oxygen,
he has obtained results which appear to equal or excel in accuracy any
which have ever been obtained in his field of work. Richards’s work has
consisted largely of improvements in apparatus. He developed the
so-called adiabatic calorimeter which practically eliminates one of the
chief errors in thermal work caused by the heating or cooling effect of
the surroundings. This modification is being generally adopted where
extremely accurate work is required.
_Organic Chemistry._
One hundred years ago qualitative tests for a few organic compounds were
known, the elements usually occurring in them were recognized, and some
of them had been analyzed quantitatively, but organic chemistry was far
less advanced than inorganic, and almost the whole of its enormous
development has taken place during our period.
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