A century of science in America : $b with special reference to the American Journal of Science, 1818-1918
History
A century of science in America : $b with special reference to the American Journal of Science, 1818-1918
American journal of science; Science -- United States -- History
The production of ammonia, which was very small a hundred years ago, has
been vastly increased in connection with the development of the
illuminating-gas industry and the employment of by-product coke ovens.
This substance is very extensively used in refrigerating machines and
also in a great many chemical operations, including the Solvay soda
process. Ammonium salts are of great importance also as fertilizers in
agriculture. The conversion of atmospheric nitrogen into ammonia on a
commercial scale is a recent achievement. It has been accomplished by
heating calcium carbide, an electric-furnace product made from lime and
coke, with nitrogen gas, thus producing calcium cyanamide, and then
treating this cyanamide with water under proper conditions. Another
method devised by Haber consists in directly combining nitrogen and
hydrogen gases under high pressure with the aid of a contact substance.
Leblanc’s method for obtaining sodium carbonate from sodium chloride by
first converting the latter into the sulphate by means of sulphuric acid
and then heating the sulphate with lime and coal in a furnace was
invented as early as 1791, but it was not rapidly developed and did not
gain a foothold in England until 1826 on account of a high duty on salt
up to that time. Afterwards the process flourished greatly in connection
with the sulphuric acid industry upon which it depended, and with the
bleaching-powder industry which utilized the hydrochloric acid
incidentally produced by it, and, of course, in connection with soap
manufacture and many other industries in which the soda itself was
employed.
About 1866 the Solvay process appeared as a rival to the Leblanc
process. This depends upon the precipitation of sodium bicarbonate from
salt solutions by means of carbon dioxide and ammonia, with the
subsequent recovery of the ammonia. It has displaced the older process
to a large extent, and it is carried on extensively in this country, for
instance, at Syracuse, New York.
Other processes for soda depend upon the electrolysis of sodium chloride
solutions. In this case caustic soda and chlorine are the direct
products, and the chlorine thus produced and liquefied by pressure in
steel cylinders, has become an important commercial article.
In earlier times wood-ashes were the source of potash and potassium
salts. Wurtz in the Journal (=10=, 326, 1850) suggested the availability
of New Jersey greensand as a source of potash and showed how this
mineral could be decomposed, but it does not appear that this mineral
has ever been utilized for the purpose. About 1861 the German
potash-salt deposits began to be developed, and these have since become
the chief source of this material. At present many efforts are being
made to obtain potassium compounds from other sources, such as brines,
cement-kiln dust, and feldspar and other minerals but thus far the
results have not satisfied the demand.
_Conclusion._
Public-domain text, read in full here on John Shaqi.
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