A History of Inventions, Discoveries, and Origins, Volume 1 (of 2)Beckmann, Johann
History
A History of Inventions, Discoveries, and Origins, Volume 1 (of 2)
Beckmann, Johann
Inventions -- History
[305] Lib. xxxv. c. 26. and lib. xxxvii. c. 9. The _lapis obsidianus_,
which Obsidius first found in Ethiopia, and made known, is undoubtedly
the same as that vulcanic glass which is sometimes called Icelandic
agate, _pumex vitreus_, and by the Spaniards, who brought it from
America and California, named _galinace_.
[306] Historiæ Augustæ Scriptores, in vita Gallieni, cap. 12.
[307] Ib. in Vopisc. vita Saturnini, c. 8.
[308] Strabo, Amst. 1707, fol. lib. xvi. p. 1099.--Some consider the
glass earth here mentioned as a mineral alkali that was really found
in Egypt, and which served to make glass; but, as the author speaks
expressly of coloured glass, I do not think that the above salt,
without which no glass was then made, is what is meant; but rather a
metallic oxide, such perhaps as ochre or manganese.
[309] Sen. Op. Lipsii, p. 579.
[310] Hist. Nat. lib. xxxvii. c. 12. A passage in Diodorus Siculus,
lib. ii. c. 52, alludes, in my opinion, to this method of colouring by
cementation.
[311] Magia Naturalis. Franc. 1591, 8vo, p. 275.
[312] Kunkel’s Ars Vitraria. Nur. 1743, 4to, pp. 98, 101.
[313] Comment. Soc. Scient. Gotting. ii. p. 41.
[314] Montamy von den Farben zuni Porzellan- und Email-malen. Leipsic,
1767, 8vo, p. 82. Fontanieu, p. 16.
[315] [The extensive use of this substance in colouring glass and
porcelain has rendered its best and most œconomical preparation
a subject of interest both to the chemist and the manufacturer.
Although the determination of its true chemical composition has
presented obstacles almost insuperable, still many important points
with regard to its manufacture have been elucidated. It has been
found that the tin salt used in precipitating it must contain both
the binoxide and protoxide of tin in certain proportions, and it has
been also discovered that the degree of dilution both of the gold
and tin solutions exerts a very perceptible influence on the beauty
of the preparation. Capaun has examined this latter point with great
attention, by testing all the different products as to their power of
colouring glass.
The first point to be attained is the preparation of a solution of
sesquioxide of tin; and for this purpose Bolley proposes to employ the
double compound of bichloride of tin with sal-ammoniac (pink salt).
This salt is not altered by exposure to the atmosphere, and contains
a fixed and known quantity of bichloride of tin, and when boiled with
metallic tin it takes up so much as will form the protochloride;
as the exact quantity of the bichloride is known, it is very easy
to use exactly such a quantity of tin as will serve to form the
sesquichloride. 100 parts of the pink salt require for this purpose
10·7 parts of metallic tin.
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