A History of Inventions, Discoveries, and Origins, Volume 2 (of 2)Beckmann, Johann
History
A History of Inventions, Discoveries, and Origins, Volume 2 (of 2)
Beckmann, Johann
Inventions -- History
Mirrors seem for a long time to have been made of a mixture of copper
and tin, as is expressly said by Pliny[153], who adds, that the best
were constructed at Brundisium. This mixture, which was known to
Aristotle, produces a white metal, which, on account of its colour, may
have been extremely proper for the purpose, and even at present the
same mixture, according to the careful experiments made by Mr. Mudge,
an Englishman[154], produces the best metal for specula. It appears
that the ancients had not determined the proportion very accurately;
for Pliny assures us twice that in his time mirrors of silver were
preferred. It is indeed not easy to ascertain the quantity of each
metal that ought to be taken, and the most advantageous degree of heat;
upon which a great deal depends. One of the principal difficulties is
to cast the metal without blisters or air-holes, and without causing
any part of the tin to oxidize, which occasions knots and cracks, and
prevents it from receiving a fine polish. A passage of Lucian[155],
which no one as yet has been able to clear up, alludes certainly, in my
opinion, to these faults. A mixture of copper and tin is so brittle,
that it is very liable to crack; and a mirror formed of it, if not
preserved with great care, soon becomes so dim, that it cannot be used
till it has been previously cleaned and polished. For this reason a
sponge with pounded pumice-stone was generally suspended, from the
ancient mirrors, and they were kept likewise in a case or box, as may
be seen by the greater part of those still extant. Mirrors of silver
were less subject to this inconvenience, and I am inclined to think
that the latter on this account made the former be disused, as we are
informed by Pliny.
As ancient mirrors of metal are still to be found in collections of
antiquities, it might be of some importance to the arts if chemical
experiments were made on their composition. Those who have hitherto
given us any account of them have contented themselves with describing
their external figure and shape. Count Caylus[156] is the only person,
as far as I know, who caused any chemical experiments to be undertaken
on this subject. They were made on a mirror found near Naples, by M.
Roux, who asserts that the composition was a mixture of copper and
regulus of antimony, with a little lead. Antimony however was not known
to the ancients. If that metal was really a component part, the mirror
must have been the work of more modern times, or it must be allowed
that the artist had metal combined with antimony without knowing it;
but the latter is not probable. The experiments made by Roux do not
seem to me to have proved in a satisfactory manner the presence of
regulus of antimony; moreover, no certain information can be derived
from them, for the antiquity of the mirror was not ascertained; nor was
it known whether it ought to be reckoned amongst the best or the worst
of the period when it was made.
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