A History of Science — Volume 3Williams, Henry Smith
History
A History of Science — Volume 3
Williams, Henry Smith
Science -- History
There is at least one form of meteor, however, of those that interested
our forebears whose meteorological importance they did not overestimate.
This is the vapor of water. How great was the interest in this familiar
meteor at the beginning of the century is attested by the number of
theories then extant regarding it; and these conflicting theories bear
witness also to the difficulty with which the familiar phenomenon of the
evaporation of water was explained.
Franklin had suggested that air dissolves water much as water dissolves
salt, and this theory was still popular, though Deluc had disproved it
by showing that water evaporates even more rapidly in a vacuum than
in air. Deluc's own theory, borrowed from earlier chemists, was that
evaporation is the chemical union of particles of water with particles
of the supposititious element heat. Erasmus Darwin combined the two
theories, suggesting that the air might hold a variable quantity of
vapor in mere solution, and in addition a permanent moiety in chemical
combination with caloric.
Undisturbed by these conflicting views, that strangely original
genius, John Dalton, afterwards to be known as perhaps the greatest
of theoretical chemists, took the question in hand, and solved it by
showing that water exists in the air as an utterly independent gas. He
reached a partial insight into the matter in 1793, when his first volume
of meteorological essays was published; but the full elucidation of
the problem came to him in 1801. The merit of his studies was at once
recognized, but the tenability of his hypothesis was long and ardently
disputed.
While the nature of evaporation was in dispute, as a matter of course
the question of precipitation must be equally undetermined. The most
famous theory of the period was that formulated by Dr. Hutton in a paper
read before the Royal Society of Edinburgh, and published in the volume
of transactions which contained also the same author's epoch-making
paper on geology. This "theory of rain" explained precipitation as due
to the cooling of a current of saturated air by contact with a colder
current, the assumption being that the surplusage of moisture was
precipitated in a chemical sense, just as the excess of salt dissolved
in hot water is precipitated when the water cools. The idea that the
cooling of the saturated air causes the precipitation of its moisture
is the germ of truth that renders this paper of Hutton's important. All
correct later theories build on this foundation.
"Let us suppose the surface of this earth wholly covered with water,"
said Hutton, "and that the sun were stationary, being always vertical in
one place; then, from the laws of heat and rarefaction, there would be
formed a circulation in the atmosphere, flowing from the dark and cold
hemisphere to the heated and illuminated place, in all directions,
towards the place of the greatest cold.
Public-domain text, read in full here on John Shaqi.
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