A History of Science — Volume 3Williams, Henry Smith
History
A History of Science — Volume 3
Williams, Henry Smith
Science -- History
Of particular interest are Howard's views as to the formation of dew,
which he explains as caused by the particles of caloric forsaking the
vapor to enter the cool body, leaving the water on the surface. This
comes as near the truth, perhaps, as could be expected while the old
idea as to the materiality of heat held sway. Howard believed, however,
that dew is usually formed in the air at some height, and that it
settles to the surface, opposing the opinion, which had gained vogue
in France and in America (where Noah Webster prominently advocated it),
that dew ascends from the earth.
The complete solution of the problem of dew formation--which really
involved also the entire question of precipitation of watery vapor in
any form--was made by Dr. W. C. Wells, a man of American birth, whose
life, however, after boyhood, was spent in Scotland (where as a young
man he enjoyed the friendship of David Hume) and in London. Inspired,
no doubt, by the researches of Mack, Hutton, and their confreres of
that Edinburgh school, Wells made observations on evaporation and
precipitation as early as 1784, but other things claimed his attention;
and though he asserts that the subject was often in his mind, he did not
take it up again in earnest until about 1812.
Meantime the observations on heat of Rumford and Davy and Leslie had
cleared the way for a proper interpretation of the facts--about the
facts themselves there had long been practical unanimity of opinion. Dr.
Black, with his latent-heat observations, had really given the clew to
all subsequent discussions of the subject of precipitation of vapor;
and from this time on it had been known that heat is taken up when water
evaporates, and given out again when it condenses. Dr. Darwin had shown
in 1788, in a paper before the Royal Society, that air gives off heat
on contracting and takes it up on expanding; and Dalton, in his essay
of 1793, had explained this phenomenon as due to the condensation and
vaporization of the water contained in the air.
But some curious and puzzling observations which Professor Patrick
Wilson, professor of astronomy in the University of Glasgow, had
communicated to the Royal Society of Edinburgh in 1784, and some similar
ones made by Mr. Six, of Canterbury, a few years later, had remained
unexplained. Both these gentlemen observed that the air is cooler where
dew is forming than the air a few feet higher, and they inferred
that the dew in forming had taken up heat, in apparent violation of
established physical principles.
It remained for Wells, in his memorable paper of 1816, to show that
these observers had simply placed the cart before the horse. He made it
clear that the air is not cooler because the dew is formed, but that
the dew is formed because the air is cooler--having become so through
radiation of heat from the solids on which the dew forms. The dew
itself, in forming, gives out its latent heat, and so tends to equalize
the temperature.
Public-domain text, read in full here on John Shaqi.
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