A History of Science — Volume 5Williams, Henry Smith
History
A History of Science — Volume 5
Williams, Henry Smith
Science -- History
Equally in the dark are we as to the explanation of that strange
affinity for its neighbors which every atom manifests in some degree.
If we assume that the power which holds one atom to another is the same
which in the case of larger bodies we term gravitation, that answer
carries us but a little way, since, as we have seen, gravitation itself
is the greatest of mysteries. But again, how chances it that different
atoms attract one another in such varying degrees, so that, for example,
fluorine unites with everything it touches, argon with nothing? And how
is it that different kinds of atoms can hold to themselves such varying
numbers of fellow-atoms--oxygen one, hydrogen two, and so on? These
are questions for the future. The wisest chemist does not know why the
simplest chemical experiment results as it does. Take, for example, a
water-like solution of nitrate of silver, and let fall into it a few
drops of another water-like solution of hydrochloric acid; a white
insoluble precipitate of chloride of silver is formed. Any tyro in
chemistry could have predicted the result with absolute certainty. But
the prediction would have been based purely upon previous empirical
knowledge--solely upon the fact that the thing had been done before
over and over, always with the same result. Why the silver forsook the
nitrogen atom and grappled the atom of oxygen no one knows. Nor can any
one as yet explain just why it is that the new compound is an insoluble,
colored, opaque substance, whereas the antecedent ones were soluble,
colorless, and transparent. More than that, no one can explain with
certainty just what is meant by the familiar word soluble itself. That
is to say, no one knows just what happens when one drops a lump of salt
or sugar into a bowl of water. We may believe with Professor Ostwald
and his followers that the molecules of sugar merely glide everywhere
between the molecules of water, without chemical action; or, on the
other hand, dismissing this mechanical explanation, we may say with
Mendeleef that the process of solution is the most active of chemical
phenomena, involving that incessant interplay of atoms known as
dissociation. But these two explanations are mutually exclusive, and
nobody can say positively which one, if either, is right. Nor is either
theory at best more than a half explanation, for the why of the strange
mechanical or chemical activities postulated is quite ignored. How is
it, for example, that the molecules of water are able to loosen the
intermolecular bonds of the sugar particles, enabling them to scamper
apart?
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