A Manual of Photographic Chemistry, Including the Practice of the Collodion ProcessHardwich, T. Frederick
Science
A Manual of Photographic Chemistry, Including the Practice of the Collodion Process
Hardwich, T. Frederick
Photographic chemistry; Photography
Rectified Ether of 750° is not to be depended on, inasmuch as the
specific gravity is often made up by adding water instead of alcohol.
Methylated Ether should be used only when economy is an object, as it is
prone to acidity and less certain in its properties.
Some of the qualities which render Ether unfit for Photographic purposes,
are as follows:--a peculiar and disagreeable smell, either of some
essential oil, or of Acetic Ether; an acid reaction to test-paper; a
property of turning alcoholic solution of Iodide of Potassium brown with
unusual rapidity; an alkaline reaction to test-paper; a high specific
gravity, from superabundance of Alcohol and water.
The Ether which has been both washed and redistilled is always the most
uniform in composition, and especially so if the second distillation be
conducted from Quicklime, Carbonate of Potash, or Caustic Potash. These
Alkaline substances retain the impurities, which are often of an acid
nature, and leave the Ether in a fit state for use.
The redistillation of Ether is a simple process: in dealing with this
fluid however the greatest caution must be exercised, on account of its
inflammable nature. Even in pouring Ether from one bottle into another, if
a light of any kind be near, the vapour is apt to take fire; and severe
injuries have been occasioned from this cause.
_Purification of Ether by redistillation from a caustic or carbonated
alkali._--Take ordinary rectified Sulphuric Ether, and agitate it with an
equal bulk of water to wash out the Alcohol; stand for a few minutes until
the contents of the bottle separate into two distinct strata, the lower of
which--_id est_, the watery stratum--is to be drawn off and rejected. Then
introduce Caustic Potash, finely powdered, in the proportion of about one
ounce to a pint of the washed Ether; shake the bottle again many times,
in order that the water--a small portion of which is still present in
solution in the Ether--may be thoroughly absorbed. Afterwards set aside
for twenty-four hours (not longer, or the Potash may begin to decompose
the Ether), when it will probably be observed that the liquid has become
yellow, and that a flocculent deposit has formed in small quantity.
Transfer to a retort of moderate capacity, supported in a saucepan of warm
water, and properly connected with a condenser. On applying a gentle heat,
the Ether distils over quietly, and condenses with very little loss; care
must be taken that none of the alkaline liquid contained in the body of
the retort finds its way, by projection or otherwise, into the neck, so as
to run down and contaminate the distilled fluid.
A more economical plan of purifying Ether is, without previous washing
with water, to agitate with Carbonate of Potash or with Quicklime, and
redistil at a moderate temperature.
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