b. _The Iodide of Ammonium._--This salt may be prepared by adding Carbonate of Ammonia to Iodide of Iron, but more easily by the following process:--A strong solution of Hydrosulphate of Ammonia is first made, by passing Sulphuretted Hydrogen gas into Liquor Ammoniæ. To this liquid, Iodine is added until the whole of the Sulphuret of Ammonium has been converted into Iodide. When this point is reached, the solution at once colours brown from solution of free Iodine. On the first addition of the Iodine, an escape of Sulphuretted Hydrogen gas and a dense deposit of Sulphur take place. After the decomposition of the Hydrosulphate of Ammonia is complete, a portion of Hydriodic Acid--formed by the mutual reaction of Sulphuretted Hydrogen and Iodine--attacks any Carbonate of Ammonia which may be present, and causes an effervescence. The effervescence being over, the liquid is still acid to test-paper, from excess of Hydriodic Acid; it is to be cautiously neutralized with Ammonia, and evaporated by the heat of a water-bath to the crystallizing point. The crystals should be thoroughly dried over a dish of Sulphuric Acid, and then sealed in tubes; by this means it will be preserved colourless. Iodide of Ammonium is very soluble in Alcohol, but it is not advisable to keep it in solution, from the rapidity with which it decomposes and becomes brown. The most common impurity of commercial Iodide of Ammonium is Sulphate of Ammonia; it is detected by its sparing solubility in Alcohol. Carbonate of Ammonia is also frequently present to a large extent, in which case an alkaline Collodion and eventually an alkaline Nitrate Bath will be produced. e. _Iodide of Cadmium._--This salt is formed by heating filings of metallic Cadmium with Iodine, or by mixing the two together with addition of water. Iodide of Cadmium is very soluble both in Alcohol and Water; the solution yielding on evaporation large six-sided tables of a pearly lustre, which are permanent in the air. The commercial Iodide is sometimes contaminated with Iodide of Zinc; the crystals being imperfectly formed and slowly liberating Iodine when dissolved in Ether and Alcohol. Pure Iodide of Cadmium remains nearly or quite colourless in Collodion, if the fluid be kept in a cool and dark place. CHAPTER II. FORMULÆ FOR SOLUTIONS REQUIRED IN THE COLLODION PROCESS. Section I.--Solutions for direct Positives. Section II.--Solutions for Negative Photographs. SECTION I. _Formulæ for Solutions for direct Positives._ The solutions are taken in the following order;--The Collodion.--The Nitrate Bath.--Developing fluids.--Fixing liquids.--Whitening solution. THE COLLODION. _Formula No. 1._ Purified Ether, sp. gr. ·720 5 fluid drachms. Purified Alcohol, sp. gr. ·825 3 " " Pyroxyline 3 to 5 grains. Pure Iodide of Cadmium or Ammonium 4 grains. _Formula No. 2._