A Manual of Photographic Chemistry, Including the Practice of the Collodion ProcessHardwich, T. Frederick
Science
A Manual of Photographic Chemistry, Including the Practice of the Collodion Process
Hardwich, T. Frederick
Photographic chemistry; Photography
Sensitizing paper with Ammonio-Nitrate.--It is not usual to float the
paper when, the Ammonio-Nitrate of Silver is used. If a bath of this
liquid were employed, it would not only become quickly discoloured by
the action of organic matter dissolved out of the papers, but would soon
contain abundance of free Ammonia (see the Vocabulary, Part III., art.
"Ammonio-Nitrate"); and an excess of Ammonia in the liquid produces an
injurious effect by dissolving away the sensitive Chloride of Silver.
The Ammonio-Nitrate is therefore applied with a glass rod, or by brushing,
and in neither case is any of the liquid which has once touched the paper
allowed to return into the bottle.
Brushes are manufactured purposely for applying Silver solutions, but the
hair is soon destroyed unless the brush be kept scrupulously clean. Lay
the salted sheet upon blotting-paper, and wet it thoroughly by drawing
the brush first lengthways and then across. Allow it to remain flat for
a minute or so, in order that a sufficient quantity of the solution may
be absorbed (you will see when it is evenly wet by looking along the
surface), and then pin up by the corner in the usual way. If, on drying,
white lines appear at the points last touched by the brush, it is probable
that the Ammonio-Nitrate contains free Ammonia.
The employment of a glass rod is a very simple and economical mode of
applying Silver solutions. Procure a flat piece of board somewhat smaller
than the sheet to be operated on, and having turned over the edges of the
paper, secure them with a pin. Next bring the board near to the corner
of the table, and laying the glass rod along the edge of the paper,
allow the fluid to drop into the groove so formed; then carry the rod
directly across the sheet, when an even wave of fluid will be spread over
the surface. A pipette made of glass tubing, when dipped into the bottle
and the upper end closed with the finger, will withdraw as much of the
Ammonio-Nitrate as is required; and if a scratch be made upon the tube at
a point corresponding to 30 or 40 minims, it will be found sufficient for
a quarter sheet of the Papier Saxe.
Ammonio-Nitrate paper, however prepared, cannot be kept many hours without
becoming brown and discoloured.
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