A Manual of Photographic Chemistry, Including the Practice of the Collodion ProcessHardwich, T. Frederick
Science
A Manual of Photographic Chemistry, Including the Practice of the Collodion Process
Hardwich, T. Frederick
Photographic chemistry; Photography
2. _Diffused Light._--_a._ In the developing room. This is a frequent
cause of fogging, and especially so when the common yellow calico
is employed, which is apt to fade. Use a treble thickness, or
procure the waterproof material, in which the pores are stopped with
gutta-percha.--_b._ In the Camera. The slide may not fit accurately, or
the door does not shut close. Throw a black cloth over the Camera during
the exposure of the plate.--_c._ From direct rays of the sun or the light
of the sky falling upon the lens. With the full aperture of a double
combination Lens, a portion of sky included in the field (as for instance
to form the background of a portrait) is apt to cause fogging. The
portrait will probably be more brilliant if a funnel-shaped canvas bag, or
a curtain with an oblong aperture admitting only the rays proceeding from
the sitter, be placed in front of the Camera.
3. _Alkalinity of the Bath._--This condition, explained at page 88, may
be due to one of the following causes:--_a._ The use of Nitrate of Silver
which has been too strongly fused (p. 13).--_b._ Constant employment of a
Collodion containing free Ammonia or Carbonate of Ammonia (p. 89).--_c._
Addition of Potash, Ammonia, or Carbonate of Soda to the Nitrate Bath, in
order to remove free Nitric Acid (p. 89).--_d._ Use of rain-water or hard
water for making the Nitrate Bath (rain-water usually contains traces of
Ammonia; hard water often abounds with Carbonate of Lime).
In either case the alkalinity may easily be removed by the addition of
Acetic Acid, one drop to four ounces of the solution. The proper mode of
testing for alkalinity is described at p. 89.
4. _Decomposition of the Nitrate Bath._--_a._ By constant exposure to
light (the injurious effects of this will be mostly seen when Positives
are taken).--_b._ By organic matter: this is sometimes present in Nitrate
of Silver which has been prepared from the residues of old Baths; or
it may be introduced by floating papers for the printing process upon
the Bath, or by dissolving the crystals of Nitrate of Silver in putrid
rain-water, or in impure distilled water collected from the condensed
water of steam-boilers and contaminated with oily matter.--_c._
Decomposition of the Bath by contact with metallic iron or copper, or with
a fixing agent, or a developing agent (p. 90).
5. _Faults of the developing solution._--a. Brown and decomposed solution
of Pyrogallic Acid; this may sometimes be used with impunity, but it
tends, as a rule, to facilitate irregular reduction of Silver.--h. Impure
Acetic Acid having a smell of Garlic and which probably contains Sulphur
in organic combination.--c. Omission of the Acetic Acid in the developer:
this will produce a universal blackness.
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