A Manual of Photographic Chemistry, Including the Practice of the Collodion ProcessHardwich, T. Frederick
Science
A Manual of Photographic Chemistry, Including the Practice of the Collodion Process
Hardwich, T. Frederick
Photographic chemistry; Photography
2. _Turbidity of the Nitrate solution._--_a._ From flakes of Iodide of
Silver having fallen away into the solution, by use of an over-iodized
Collodion.--_b._ From a deposit formed by degrees upon the sides of the
gutta-percha trough.--_c._ From the inside of the trough being dusty at
the time of pouring in the solution.
In order to obviate these inconveniences, it is well to make at least half
as much again of the Nitrate solution as is necessary, and to keep it in a
stock-bottle, from which the upper part may be poured off when required.
The frequent filtration of Silver Baths is unadvisable, since the paper
employed may be contaminated with impurities.
3. _Dust upon the surface of the glass at the time of pouring on the
Collodion._--Perfectly clean glasses, if set aside for a few minutes,
acquire small particles of dust; each plate should therefore be gently
wiped with a silk handkerchief immediately before being used.
4. _Faults of the Slide._--Sometimes a small hole exists, which admits a
pencil of light, and produces a spot, known by its being always in the
same part of the plate; occasionally the door works too tightly so that
small particles of wood, etc., are scraped off, and projected against the
plate when it is raised. Or perhaps the operator, after the exposure is
finished, shuts down the door with a jerk, and so causes a splash in the
liquid which has drained down and accumulated in the groove below; this
cause, although not a common one, may sometimes occur.
5. _Insoluble particles in the Pyrogallic Acid._--The solution of
Pyrogallic Acid will not usually require filtering, but if specks of
Metagallic Acid are present, the developer should be passed through
blotting paper before use.
Spots of Transparency may generally be traced to some cause
_which renders the Iodide of Silver insensible to light at particular
points_, so that on the application of the developer no reduction takes
place.
1. _Concentration of the Nitrate of Silver on the surface of the film by
evaporation._--When the film becomes too dry after removal from the Bath,
the solvent power of the Nitrate increases so much that it eats away the
Iodide and produces spots.
2. _Small particles of undissolved Iodide of Potassium in the
Collodion._--These are likely to occur when Anhydrous Ether and Alcohol
are employed. They produce transparent specks at every part of the plate.
Allow the Collodion to settle, or add a drop of water, which will dissolve
the Iodide.
3. _Alcohol or Ether containing too much water_.--This causes a
reticulated appearance of the film, which is rotten and full of holes.
4. _Use of glasses improperly cleaned._--This cause is perhaps the most
frequent of all, when the film of Pyroxyline is very thin and the Bath
neutral. After glasses have been long used it is often difficult to clean
them so thoroughly that the breath lies smoothly; but the use of Potash
gives the best chance.
MARKINGS OF VARIOUS KINDS ON COLLODION PLATES.
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