A Manual of Photographic Chemistry, Including the Practice of the Collodion ProcessHardwich, T. Frederick
Science
A Manual of Photographic Chemistry, Including the Practice of the Collodion Process
Hardwich, T. Frederick
Photographic chemistry; Photography
10. _Marks from the developer not running up to the edge of the film_ (p.
212). Remedy this as far as possible by allowing the Collodion to set a
little more firmly before dipping the plate in the Bath.
IMPERFECTIONS IN COLLODION NEGATIVES.
1. _A want of Intensity._--a. From the development not having been
sufficiently pushed (p. 224).--_b._ From the Collodion film being too
blue and transparent for Negatives.--_c._ The Collodion newly made from
pure materials (p. 114).--_d._ The plate kept too long between exciting
and development (p. 100).--_e._ The Bath newly prepared from commercial
crystallized Nitrate of Silver (p. 101).--_f._ The light too feeble, as on
very dark wintry days, or in copying interiors, etc.
2. _Inferior half-tones, with great intensity of the high Lights._--_a._
From the plate being insufficiently exposed.--_b._ The Collodion of
inferior quality, either too strongly tinted with Iodine or made
from impure materials.--_c._ The Nitrate Bath old and partially
decomposed.--_d._ The light reflected too strongly from the object. When
the light is unusually bright, a feeble Collodion and a newly mixed
Nitrate Bath will be found to give better definition in the high lights
than an intense Collodion, which may produce chalky Negatives.
3. _The image pale and misty._--The plate is over-exposed (if so, the
image will probably be a reddish-brown colour by transmitted light), or
there is diffused light in the Camera or developing room. The presence of
Bromides or Chlorides in the Collodion may occasionally produce the same
effect.
4. _The high lights of the image are solarized._--A change of colour to
a light brown or red tint by transmitted light, with a dark shade by
reflected light, is favoured by over-exposure of the plate, by organic
decomposition of the Collodion, and by Acetate of Silver and other organic
bodies in the Bath.
5. _The image dissolves off on applying the Cyanide of Potassium._--The
Collodion is probably over-iodized. The same thing may also happen in
the Honey preservative process, when the plates have been long kept and
the indurated layer of syrup not properly removed before applying the
developer.
6. _The developer does not run up to the edge of the film._--This is
likely to occur when using Collodion nearly anhydrous; and particularly
so with a new Bath not containing much Alcohol. The film will be less
repellent, if a longer time be allowed before dipping in the Bath.
7. _The film does not stick to the glass._--Clean the plates very
carefully, and make the Collodion a little thinner if required. Allow
a longer time before dipping in the Bath. A very effectual plan is to
roughen the surface of the plates, about an eighth of an inch round the
edges.
IMPERFECTIONS IN COLLODION POSITIVES.
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