A Manual of Photographic Chemistry, Including the Practice of the Collodion ProcessHardwich, T. Frederick
Science
A Manual of Photographic Chemistry, Including the Practice of the Collodion Process
Hardwich, T. Frederick
Photographic chemistry; Photography
8. _Vertical lines, and mistiness, on the image._--If the Bath has been
much used, add to it a third part of a simple solution of Nitrate of
Silver in water, without any Alcohol or Iodide. Also prepare the developer
with addition of Alcohol, to make it flow more readily (p. 211).
SECTION II.
_Imperfections in Paper Positives._
1. _The Print marbled and spotty._--The quality of the paper is often
inferior, which causes it to imbibe liquids unevenly at different points;
or the amount of Silver in the Nitrate Bath is insufficient. In this case
the spots are often absent at the lower and most depending part of the
sheet, where the excess of liquid drains off.
2. _The Print clean on the surface, but spotted when held up to the
light._--In this case the spots are probably due to imperfect fixation
(see p. 129).
3. _The Print becomes pale in the Hyposulphite Bath, and has a cold and
faded appearance when finished._--The Chloride of Silver in the paper may
have been in excess with regard to the free Nitrate of Silver; which is
especially likely if no bronzing could be obtained by prolonged action of
the light, or if a weak solution of Nitrate of Silver was laid on with a
brush, or by a glass rod. Prints formed on paper which has been kept too
long after sensitizing present the same appearance, the free Nitrate of
Silver having entered into combination with the organic matter.
4. _Yellowness of the light parts of the proof._--The following causes
are likely to produce yellowness:--acidity of the fixing and toning Bath
(p. 139),--its action continued for too long a time,--the first washings
of the proof not performed quickly,--the toning Bath laid aside until it
had become decomposed and nearly useless,--the paper kept for several days
after sensitizing.
A creamy yellowness is also common in Prints toned by Sel d'or, when the
Hydrochloric Acid has been omitted from the formula; the proof exposed to
light during the toning and fixing process; or too long a time allowed to
elapse between the toning and fixing. It is also more frequently met with
on albuminized paper.
5. _Intense bronzing of the deep shadows._--In this case the Negative
is in fault; remedy the evil as far as possible by printing on paper
containing but little salt.
6. _The definition of the Print imperfect, the Negative being a good
one._--Much will depend upon the quality of the paper. Towgood's Positive
gives good definition. The use of Albumen will be a great advantage.
Citrate of Soda (p. 246) will also improve the definition on plain paper.
7. _Markings of a yellow tint in the dark portions of the
Positive._--These are common on Prints toned without Gold; care should
be taken not to handle the paper too much, either before or after
sensitizing; to wash the prints in a clean vessel; and not to lay them
down whilst wet on a wooden table or in contact with anything likely to
communicate impurities.
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