A Manual of Photographic Chemistry, Including the Practice of the Collodion ProcessHardwich, T. Frederick
Science
A Manual of Photographic Chemistry, Including the Practice of the Collodion Process
Hardwich, T. Frederick
Photographic chemistry; Photography
_Development of the Image._--Make a saturated solution of Gallic Acid in
water by the directions given at page 261. Then dissolve forty grains
of pure Nitrate of Silver in one ounce of distilled water. Pour into a
flat porcelain dish a sufficient quantity of the Gallic Acid solution to
flood the plate readily. Then measure it, and to each fluid ounce add
_ten minims_ of the solution of Silver, or five minims in hot weather. It
is important that no discoloration should occur on mixing these liquids
together, to obviate which, observe the following precautions:--Clean the
porcelain vessel very carefully with Nitric Acid or Cyanide before use.
Employ a pure solution of Nitrate of Silver; and mix it with the Gallic
Acid, in preference to adding the Gallic Acid to the Silver solution (read
the remarks at p. 179).
The picture may be expected to appear in five or ten minutes, and in
one hour, or from that to four hours (p. 298), the development will be
complete. It will not be necessary to keep the plates in motion, but
simply to lay them side by side in the solution of the Gallic Acid. If
in spite of all precautions the developer begins to blacken before the
intensity has reached the proper point, it must be poured off and a fresh
mixture prepared. This however will not often happen.
Lastly, when a full amount of opacity has been obtained, wash the plate
with water, and fix it in a solution of Hyposulphite of Soda, or dilute
solution of Cyanide of Potassium.
_Failures in the process._--Stains in the development may arise from
using dirty dishes, or glasses which have been left in Gallo-Nitrate
of Silver and improperly cleaned. It must be borne in mind that these
impurities are not visible to the eye, although they produce the effect of
discolouring the developer. A thorough cleansing with strong Nitric Acid
or Potash will prove a remedy.
Blisters, unless of large size, may often be disregarded, as they
disappear on drying. General cloudiness may depend upon the film having
been imperfectly washed. Irregular reduction at certain parts may be due
to the Gelatine setting before the plate has become dry, or to stains
produced by the finger applied to the upper edge of the plate.[54]
[54] Since the above was written, Mr. Maxwell Lyte has communicated to the
'Photographic Journal' (vol. iii.) a dry process in which a _modified_
Gelatine is used. The change is produced by boiling a solution of gelatine
with dilute Sulphuric Acid, which is afterwards neutralized and removed by
means of chalk. The result is to destroy the gelatinizing property of the
animal substance; the solution retains its fluidity on cooling, and the
necessity of employing artificial heat in drying the plates is avoided.
PART III.
OUTLINES or GENERAL CHEMISTRY.
OUTLINES or GENERAL CHEMISTRY.
[Illustration]
CHAPTER I.
THE CHEMICAL ELEMENTS AND THEIR COMBINATIONS.
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