A Manual of Photographic Chemistry, Including the Practice of the Collodion ProcessHardwich, T. Frederick
Science
A Manual of Photographic Chemistry, Including the Practice of the Collodion Process
Hardwich, T. Frederick
Photographic chemistry; Photography
Compound bodies however do not, as a rule, unite with simple elements. In
illustration, take the action of Nitric Acid upon Silver, described at
page 12. No effect is produced upon the metal until _Oxygen_ is imparted;
then the Oxide of Silver so formed dissolves in the Nitric Acid. In other
words, it is necessary that a binary compound should be first formed,
before the solution can take place. The mutual attraction or chemical
affinity exhibited by compound bodies is, as in the case of elements, most
strongly marked when the two substances are opposed to each other in their
general properties.
Thus, _acids_ do not unite with other acids, but they combine instantly
with _alkalies_; the two mutually neutralizing each other and forming "a
salt."
_Salts_ therefore are ternary compounds produced by the union of acids and
bases; common Salt, formed by neutralizing Muriatic Acid with Soda, being
taken as the type of the whole class.
_General characters of the Salts._--An aqueous solution of Chloride of
Sodium, or common Salt, possesses those characters which are usually
termed saline; it is neither sour nor corrosive, but, on the other hand,
has a cooling agreeable taste. It produces no effect upon litmus and other
vegetable colours, and is wanting in those energetic reactions which are
characteristic of both acids and alkalies; hence, although formed by the
union of two binary compounds, it differs essentially in properties from
both.
All salts however do not correspond to this description of the properties
of Chloride of Sodium. The Carbonate of Potash, for instance, is an
acrid and alkaline salt, and the Nitrate of Iron reddens litmus-paper.
A perfectly neutral salt is formed when a strong acid unites with an
energetic base; but if, of the two constituents, one is more powerful than
the other, the properties of that one are often seen in the resulting
salt. Thus the Carbonate of Potash is _alkaline_ to test-paper, because
the Carbonic Acid is feeble in its reactions; but if _Nitric Acid_ and
_Potash_ are brought together, then a Nitrate of Potash is produced, which
is neutral in every sense of the term.
The Chloride of Sodium and salts of a similar kind are freely soluble in
water, but all salts are not so. Some dissolve only sparingly, and others
not at all. The Chloride and Iodide of Silver are examples of the latter
class; they are not bitter and caustic like the Nitrate of Silver, but are
perfectly tasteless from being insoluble in the fluids of the mouth.
It is seen therefore from these examples, and many others which might
be adduced, that the popular notion of a saline body is far from being
correct, and that, in the language of strict definition, any substance
is a salt which is produced by the union of an acid with an alkali,
independent of the properties it may possess.
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