A Manual of Photographic Chemistry, Including the Practice of the Collodion ProcessHardwich, T. Frederick
Science
A Manual of Photographic Chemistry, Including the Practice of the Collodion Process
Hardwich, T. Frederick
Photographic chemistry; Photography
_Properties._--Bromine is a deep reddish-brown liquid of a disagreeable
odour, and fuming strongly at common temperatures; sparingly soluble
in water (1 part in 23, Löwig), but more abundantly so in Alcohol, and
especially in Ether. It is very heavy, having a specific gravity of 3·0.
Bromine is closely analogous to Chlorine and Iodine in its chemical
properties. It stands on the list intermediately between the two; its
affinities being stronger than those of Iodine, but weaker than Chlorine
(see Chlorine).
It forms a large class of salts, of which the Bromides of Potassium,
Cadmium, and Silver are the most familiar to Photographers.
BROMIDE OF POTASSIUM.
Symbol, KBr. Atomic weight, 118.
Bromide of Potassium is prepared by adding Bromine to Caustic Potash,
and heating the product, which is a mixture of Bromide of Potassium and
Bromate of Potash, to redness, in order to drive off the Oxygen from the
latter salt. It crystallizes in anhydrous cubes, like the Chloride and
Iodide of Potassium; it is easily soluble in water, but more sparingly so
in Alcohol; it yields red fumes of Bromine when acted upon by Sulphuric
Acid.
BROMIDE OF SILVER. _See_ Silver, Bromide of.
CARBONATE OF SODA.
Symbol, NaO CO{2} + 10 Aq.
This salt was formerly obtained from the ashes of seaweeds, but is
now more economically manufactured on a large scale from common salt.
The Chloride of Sodium is first converted into Sulphate of Soda, and
afterwards the Sulphate into Carbonate of Soda.
_Properties._--The perfect crystals contain ten atoms of water, which
are driven off by the application of heat, leaving a white powder--the
anhydrous Carbonate. _Common Washing Soda_ is a neutral Carbonate,
contaminated to a certain extent with Chloride of Sodium and Sulphate of
Soda. The Carbonate used for effervescing draughts is either a Bicarbonate
with 1 atom of water, or a Sesquicarbonate, containing about 40 per cent,
of real alkali; it is therefore nearly double as strong as the washing
Carbonate, which contains about 22 per cent, of Soda. Carbonate of Soda is
soluble in twice its weight of water at 60°, the solution being strongly
alkaline.
CARBONATE OF POTASH. See Potash, Carbonate of.
CASEINE. _See_ Milk.
CHARCOAL, ANIMAL.
Animal Charcoal is obtained by heating animal substances, such as bones,
dried blood, horns, etc., to redness, in close vessels, until all
volatile empyreumatic matters have been driven off, and a residue of
Carbon remains. When prepared from bones it contains a large quantity of
inorganic matter in the shape of Carbonate and Phosphate of Lime, the
former of which produces _alkalinity_ in reacting upon Nitrate of Silver
(see p. 89). Animal Charcoal is freed from these earthy salts by repeated
digestion in Hydrochloric Acid; but unless very carefully washed it is apt
to retain an acid reaction, and so to liberate free Nitric Acid when added
to solution of Nitrate of Silver.
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