A Manual of Photographic Chemistry, Including the Practice of the Collodion ProcessHardwich, T. Frederick
Science
A Manual of Photographic Chemistry, Including the Practice of the Collodion Process
Hardwich, T. Frederick
Photographic chemistry; Photography
SILVER, NITRITE OF.
Symbol, AgO NO{3}. Atomic weight, 154.
Nitrite of Silver is a compound of Nitrous Acid, or NO{3}, with Oxide of
Silver. It is formed by heating Nitrate of Silver, so as to drive off a
portion of its Oxygen, or more conveniently, by mixing Nitrate of Silver
and Nitrite of Potash in equal parts, fusing strongly, and dissolving in a
small quantity of boiling water: on cooling, the Nitrite crystallizes out,
and may be purified by pressing in blotting-paper. Mr. Hadow describes
an economical method of preparing Nitrite of Silver in quantity, viz. by
heating 1 part of Starch in 8 of Nitric Acid of 1·25 specific gravity,
and conducting the evolved gases into a solution of pure Carbonate of
Soda until effervescence has ceased. The Nitrite of Soda thus formed is
afterwards added to Nitrate of Silver in the usual way.
_Properties._--Nitrite of Silver is soluble in 120 parts of cold water;
easily soluble in boiling water, and crystallizes, on cooling, in long
slender needles. It has a certain degree of affinity for Oxygen, and tends
to pass into the condition of Nitrate of Silver; but it is probable that
its Photographic properties depend more upon a decomposition of the salt
and liberation of Nitrous Acid.
_Properties of Nitrous Acid._--This substance possesses very feeble
acid properties, its salts being decomposed even by Acetic Acid. It is
an unstable body, and splits up, in contact with water, into Binoxide
of Nitrogen and Nitric Acid. The Peroxide of Nitrogen, NO{4}, is also
decomposed by water, and yields the same products.
SILVER, ACETATE OF.
Symbol, AgO (C{4}H{3}O{3}). Atomic weight, 167.
This is a difficultly soluble salt, deposited in lamellar crystals when
an Acetate is added to a strong solution of Nitrate of Silver. If _Acetic
Acid_ be used in place of an Acetate, the Acetate of Silver does not fall
so readily, since the Nitric Acid which would then be liberated impedes
the decomposition. Its properties have been sufficiently described at page
89.
SILVER, HYPOSULPHITE OF.
Symbol, AgO S{2}O{2}. Atomic weight, 164.
This salt is fully described in Part I. page 129. For the properties of
the soluble double salt of Hyposulphite of Silver and Hyposulphite of
Soda, see page 43.
SUGAR OF MILK. _See_ Milk.
SULPHURETTED HYDROGEN. _See_ Hydrosulphuric Acid.
SULPHURIC ACID.
Symbol, SO{3}. Atomic weight, 40.
Sulphuric Acid may be formed by oxidizing Sulphur with boiling Nitric
Acid; but this plan would be too expensive to be adopted on a large
scale. The commercial process for the manufacture of Sulphuric Acid is
exceedingly ingenious and beautiful, but it involves reactions which are
too complicated to admit of a superficial explanation. The Sulphur is
first burnt into gaseous Sulphurous Acid (SO{2}), and then by the agency
of Binoxide of Nitrogen gas, an additional atom of Oxygen is imparted from
the atmosphere, so as to convert the SO{2} into SO{3}, or Sulphuric Acid.
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