A Manual of Photographic Chemistry, Including the Practice of the Collodion ProcessHardwich, T. Frederick
Science
A Manual of Photographic Chemistry, Including the Practice of the Collodion Process
Hardwich, T. Frederick
Photographic chemistry; Photography
The process for reducing Chloride of Silver in the moist way, by metallic
Zinc and Sulphuric Acid, is more economical and less troublesome than
that just given; it is conducted as follows:--The Chloride, after having
been well washed as before, is placed in a large flat dish, and a bar
of metallic Zinc laid in contact with it. A small quantity of Oil of
Vitriol, diluted with four parts of water, is then added, until a slight
effervescence of Hydrogen gas is seen to take place. The vessel is set
aside for two or three days, and is not to be disturbed, either by
stirring or by moving the bar. The reduction begins with the Chloride
immediately in contact with the Zinc, and radiates in all directions. When
the whole mass has become of a grey colour, the bar is to be carefully
removed and the adhering Silver washed off with a stream of water; the
Zinc usually presents a honeycombed appearance, with irregularities upon
the surface, which however are not metallic Silver;--they consist only of
Zinc or of Oxide of Zinc.
In order to ensure the purity of the Silver, a fresh addition of Sulphuric
Acid must be made, after the Zinc bar has been removed, and the digestion
continued for several hours, in order to dissolve any fragments of
metallic Zinc which may have been inadvertently detached. The grey powder
must be repeatedly washed, first with Sulphuric Acid and water (this is
necessary to dissolve a portion of an insoluble Salt of Zinc, probably
an oxychloride) and then with water alone, until the liquid runs away
_neutral_, and gives no precipitate with Carbonate of Soda; it may
then be fused into a button, to burn off organic matter if present, and
subsequently converted into Nitrate of Silver by boiling with Nitric Acid
diluted with two parts of water.
In reducing Chloride of Silver precipitated from old Nitrate Baths
_containing Iodide of Silver_, the grey metallic powder is sometimes
contaminated with unreduced Iodide of Silver, which dissolves in
the solution of Nitrate of Silver formed on treating the mass with
Nitric Acid. To avoid this, wash the purified Silver with solution of
Hyposulphite of Soda, and then again with water.
MODE OF TAKING THE SPECIFIC GRAVITY OF LIQUIDS.
Instruments are sold, termed "Hydrometers," which indicate specific
gravity by the extent to which a glass bulb containing air, and properly
balanced, rises or sinks, in the liquid; but a more exact process, and one
equally simple, is by the use of the specific gravity bottle.
These bottles are made to contain exactly 1000 grains of distilled water,
and with each is sold _a brass weight_, which counterbalances it when
filled with pure water.
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