A Manual of Photographic Chemistry, Including the Practice of the Collodion ProcessHardwich, T. Frederick
Science
A Manual of Photographic Chemistry, Including the Practice of the Collodion Process
Hardwich, T. Frederick
Photographic chemistry; Photography
_Mode of Washing Precipitates._--Collect the precipitate upon a filter and
drain off as much of the mother-liquor as possible; then pour in distilled
water by small portions at a time, allowing each to percolate through the
deposit before adding a fresh quantity. When the water passes through
perfectly pure, the washing is complete; in testing it, a single drop
may be laid upon a strip of glass and allowed to evaporate spontaneously
in a warm place, or the proper chemical reagents may be applied, and the
washing continued until no impurity can be detected. Thus, for example,
in washing the Sulphuret of Silver precipitated from a Hypo-Bath by means
of Hydrosulphate of Ammonia, the process will be completed when the water
which runs through causes no deposit with a drop of Nitrate of Silver
solution.
ON THE USE OF TEST-PAPERS.
The nature of the colouring matter which is employed in the preparation of
litmus-paper has already been described at page 353.
In testing for the alkalies and basic oxides generally, the blue
litmus-paper which has been reddened by an acid may be used, or, in place
of it, the _turmeric_-paper. Turmeric is a yellow vegetable substance
which possesses the property of becoming brown when treated with an
alkali; it is however less sensitive than the reddened litmus, and is
scarcely affected by the weaker bases, such as Oxide of Silver.
In using test-papers, observe the following precautions:--they should be
kept in a dark place, and protected from the action of the air, or they
soon become purple from Carbonic Acid, always present in the atmosphere
in small quantity. By immersion in water containing about one drop of
Liquor Potassæ or Ammoniæ, or a grain of Carbonate of Soda to four
ounces, the blue colour is restored. As the quantities which are tested
for in Photography are often infinitesimally small, it is essential that
the litmus-paper should be in good condition; and test-papers prepared
with porous paper will be found to show the colour better than those
upon glazed or strongly-sized paper. The mode of employing the paper is
as follows:--Place a small strip in the liquid to be examined: if it
becomes at once _bright red_, a strong acid is present; but if it changes
_slowly to a wine-red_ tint, a weak acid, such as Acetic or Carbonic, is
indicated. In the case of the Photographic Nitrate Bath faintly acidified
with Acetic Acid, a purple colour only may be expected, and a decided red
colour would suggest the presence of Nitric Acid. In the Hypo fixing and
toning Bath which has acquired acidity, the litmus-paper will perhaps
redden in about three or four minutes.
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