A Manual of Photographic Chemistry, Including the Practice of the Collodion ProcessHardwich, T. Frederick
Science
A Manual of Photographic Chemistry, Including the Practice of the Collodion Process
Hardwich, T. Frederick
Photographic chemistry; Photography
f. _Addition of Bromide or Chloride to Collodion._--In the Daguerreotype
a very exalted state of sensibility is obtained by exposing the silvered
plate first to the vapour of Iodine, and afterwards to that of Bromine or
Chlorine; but this rule does not apply to the Collodion process, which
differs essentially in principle. Soluble Bromides added to Collodion
lessen its sensibility to an appreciable extent, as also do Chlorides.
This rule however may perhaps be liable to an exception when artificial
light is used, which contains a greater proportion of the rays of small
refrangibility, known to act more powerfully upon the Bromide than upon
the Iodide of Silver (p. 66).
g. _Density of the sensitive film._--When the proportion of soluble Iodide
in the iodizing solution is too great, the film is very dense, and the
Iodide of Silver is apt to burst out upon the surface, and fall away in
loose flakes into the Bath. This condition, which is highly unfavourable
to sensitiveness, is very common in Collodion, and constitutes what is
termed "over-iodizing." The Iodide, in fact, is formed in such a case too
much upon the surface, and consequently, when the fixing agent is applied,
the image not being retained by the film, is washed off and lost.
On the other hand, the sensibility of the film is not lessened by reducing
the amount of Iodide in Collodion to a minimum, if all the solutions are
neutral; but the pale blue films formed by a dilute Collodion, and which
almost rival the Daguerreotype itself in delicacy, are nearly useless in
practice; for if free Iodine or other bodies of a retarding nature are
present in any quantity, either in the Collodion or in the Bath, they
almost destroy the action of a weak light, producing a far more injurious
effect than if the film were more yellow and opaque.
h. _Impurities in Ether and Alcohol._--Pure Ether should be neutral to
test-paper, but the commercial samples of this article have usually either
an acid or an alkaline reaction. The frequent occurrence of a peculiar
oxidizing principle in Ether has also been pointed out (p. 85). Each of
these three conditions is injurious to sensitiveness; the first and last
by liberating Iodine when alkaline Iodides are used; and the second,
by producing Iodoform under the same circumstances. In this case the
Collodion remains colourless, but gives inferior results.
The Author has also observed that Ether which has been redistilled from
the residues of Collodion may contain a volatile principle (probably a
compound Ether?) which produces a retarding effect upon the action of
light.
Commercial Spirit of Wine is not always uniform in composition, as
sufficiently evidenced by the test of smell. It may contain "fusel oil" or
other volatile substances, which become milky on dilution with water, and
are believed to injure the quality of the spirit for Photographic use.
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