A Manual of Photographic Chemistry, Including the Practice of the Collodion ProcessHardwich, T. Frederick
Science
A Manual of Photographic Chemistry, Including the Practice of the Collodion Process
Hardwich, T. Frederick
Photographic chemistry; Photography
Hence we see, that, to produce a good print, it is essential that the
Negative should possess considerable intensity in the dark parts. Pale
and feeble Negatives yield proofs which are wanting in vigour, and have
a flat and indistinct appearance. The combination cannot be exposed to
light for a sufficient length of time to bring about the requisite degree
of reduction of the Chloride of Silver; and hence the deepest shadows of
the resulting Positive are not sufficiently dark, and there is _a want of
contrast_ which is fatal to the effect.
A good Negative should be so opaque as to preserve the lights of the
printed image beneath clear, _until the darkest shades are about to pass
into the bronze or coppery condition_. If the amount of intensity be less
than this, the finest effect cannot be obtained.
CONDITIONS AFFECTING THE SENSITIVENESS OF THE PAPER AND THE INTENSITY OF
THE IMAGE.
Some of the principal of these are as follows:--
a. _The Strength of the Salting Bath._--The sensibility of the paper is
regulated up to a certain point by the amount of salt[16] used in the
preparation. The quantity of alkaline Chloride determines the amount of
Chloride of Silver; and with a proper excess of Nitrate of Silver, papers
are to a certain point more sensitive in proportion as they contain more
of the Chloride.
[16] The difference in the atomic weights of the various soluble Chlorides
used in salting must be borne in mind. Ten grains of Chloride of Ammonium
contain as much Chlorine as eleven of Chloride of Sodium, or twenty-two
grains of Chloride of Barium. (See the Vocabulary, Part III.)
Highly sensitized papers darken rapidly, and pass very completely into the
bronze stage. Those containing less Chloride darken more slowly, and do
not become bronzed with the same intensity of light. A Photographic print,
formed upon paper highly salted and sensitized, is usually vigorous, with
great contrast of light and shade; particularly so when the printing is
conducted in a strong light. Hence it will be an advantage, with a feeble
Negative, and in dull weather, to _double_ the ordinary quantity of Salt,
whereas in the case of an intense Negative, and with direct sunlight, the
deep shadows will be too much bronzed unless the quantity of Chloride and
Nitrate of Silver in the paper be kept low.
In proportion as Photographic papers are highly salted and sensitized,
they become more prone to change colour spontaneously in the dark.
b. _Proportion of Nitrate of Silver._--The compound on which a positive
print is formed is a Chloride, or an organic Salt of Silver, _with
an excess of Nitrate of Silver_. Nothing is gained by increasing the
proportion of Chloride of Sodium, unless at the same time an addition be
made to the quantity of free Nitrate in the sensitizing Bath.
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