A Manual of Photographic Chemistry, Including the Practice of the Collodion ProcessHardwich, T. Frederick
Science
A Manual of Photographic Chemistry, Including the Practice of the Collodion Process
Hardwich, T. Frederick
Photographic chemistry; Photography
e. _Impurities in Nitrate of Silver._--Nitrate of Silver used for
Photographic printing should be free from even a trace of Protonitrate of
Mercury, since it is known that the precipitation of Chloride of Mercury
prevents the darkening of Chloride of Silver by light.
The peculiar condition of Nitrate of Silver spoken of at page 101, in
which it is thought to contain Oxides of Nitrogen, is likely to interfere
with Photographic printing. This is probably the explanation of a
faulty state of the Nitrate solution, in which it yields red and feeble
positives, and does not darken in colour in exciting albuminized paper.
The remedy will be, to fuse the Nitrate of Silver at a moderate heat
before dissolving it.
THE COLOUR OF THE IMAGE INFLUENCED BY THE PREPARATION OF THE SENSITIVE
PAPER.
This subject should be studied by those who desire to print with taste.
By introducing a few simple modifications into the mode of preparing the
sensitive paper, almost any variety of tint may be obtained.
The tendency of the "toning" process, to which the print is afterwards to
be submitted, is to darken the colour, and, if gold be used, to give a
shade of _blue_. Hence, if the Positive be printed of a red tone, it will
change in the gold Bath to a purple; whereas if left, after exposure to
light and fixing, of a dark brown or sepia tint, it passes by toning into
a pure black.
The Positive should look warm and bright on its removal from the printing
frame; but the tint which remains after immersion in Hyposulphite of Soda
is the proper colour of the simply fixed print.
The following points may be mentioned as affecting the colour and general
appearance of the picture.
a. _The proportions of Salt and Nitrate of Silver._--Highly salted and
sensitized papers give a _darker_ image than those which, containing a
small proportion of Chloride of Silver, are less sensitive to light.
Hence in printing upon paper weakly sensitized, in order to bring out the
finer details of a highly intense negative, we find the image unusually
red after fixing, and of a brown or mulberry colour when toned. The above
remarks apply also in some degree to the strength of the Nitrate Bath, and
especially so when no organic matter excepting Gelatine is employed,--in
such a case the image will be _darker_ after fixing, if the proportion of
free Nitrate of Silver be large.
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