A new system of chemical philosophy, Volume 2, Part 1Dalton, John
Science
A new system of chemical philosophy, Volume 2, Part 1
Dalton, John
Atomic theory; Chemistry, Inorganic
From the experiments of Margraff and Pelletier, it seems probable
that phosphorus unites both with arsenic and its oxide. By distilling
a mixture of equal parts of arsenic and phosphorus in a carefully
regulated heat, Pelletier obtained a residuum of a black shining
substance, containing a good proportion of phosphorus. The same was
obtained in the humid way, by keeping phosphorus in fusion on arsenic
under water for some time. The phosphuretted oxide may be obtained by
distilling phosphorus and the white oxide of arsenic together, the
phosphuretted oxide sublimes mixed with arsenic and phosphorus in a
separate state. It is of a red colour. The proportions in neither case
were ascertained. It is probable that the compounds are of the most
simple kind, or one atom to one; in that case we shall have 21 arsenic
and 9⅓ phosphorus, or 100 arsenic and 44 phosphorus for phosphuret of
arsenic; and 28 oxide and 9⅓ phosphorus, or 100 oxide and 33 phosphorus
for phosphuretted oxide.
No precipitation is occasioned by phosphuretted hydrogen water in
solutions of arsenic.
23. _Phosphuret of cobalt._
Cobalt unites with phosphorus in the direct way as well as by being
heated with phosphoric glass. The colour of the compound is a blueish
white; it is brittle and crystalline in the fracture. The metal
acquires 7 per cent.; this is below the theoretic quantity, which is 25
per cent. if the atom of cobalt be 37.
Solutions of cobalt give no precipitate by phosphuretted hydrogen water.
24. _Phosphuret of manganese._
This compound may be formed like the preceding ones. It is of a white
colour, brittle and of a granular texture. It is not liable to be
altered by the air like the pure metal. The proportions of the compound
Pelletier did not determine. Reasoning from theory, it should consist
of 25 metal and 9⅓ phosphorus; or 100 metal and 37 phosphorus.
The salts and oxide of manganese are not sensibly affected by
phosphuretted hydrogen water.
* * * * *
The combinations of the remaining metals with phosphorus can scarcely
be said to have been investigated.
SECTION 16.
CARBURETS.
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