A new system of chemical philosophy, Volume 2, Part 1Dalton, John
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A new system of chemical philosophy, Volume 2, Part 1
Dalton, John
Atomic theory; Chemistry, Inorganic
[Footnote 24: The result for this last article must be considered more
uncertain than any of the previous ones, the experiment being more
complicated.]
They found the specific heats of equal volumes of air of the pressures
29.2 and 41.7 inches of mercury to be nearly as 1 ∶ 1.2396, differing
from the ratio of the pressures or densities, which is 1: 1.358.
The above table of the specific heat of the permanent gases (excluding
aqueous vapour) was corroborated by the results of another series of
experiments in which the principle was varied a little: namely, to find
how many cubic inches of each gas at a given temperature were required
to raise the temperature of the calorimeter a given number of degrees,
and inferring the capacities for heat to be inversely as the quantities
of gas employed. The differences in the results were from 1 to 10 per
cent., which may be considered small, in experiments of such delicacy.
The ratios of the specific heats of several gases being found, it was
highly expedient to find the ratio of the specific heat of water, and
that of some one gas, as common air. This was effected by passing a
small current of hot water through the calorimeter, and comparing
the effect of this current with that of the larger one of air, the
requisite care being taken to ascertain the quantity of water passing
in a given time and its temperature at the ingress. The result of this
experiment was that the specific heat of water is to that of common air
as 1 ∶ .25 nearly. By two other experiments, varied from the above,
results not much differing were obtained, so that the average of the
three gave, water to air, as 1 ∶ .2669.
Reducing the specific heats of the gases to the standard of water as
unity, we have the following Table of the specific heats of equal
weights of the respective bodies:
Water 1.0000
Air 0.2669
Hydrogen 3.2936
Carbonic Acid 0.2210
Oxygen 0.2361
Azote 0.2754
Nitrous Oxide 0.2369
Olefiant Gas 0.4207
Carbonic Oxide 0.2884
Aqueous Vapour 0.8474
Before we animadvert upon these results, it will be expedient to give
an abstract of the not less interesting experiments of Messrs. Dulong
and Petit, on heat, as given in the Annales de Chimie and de Physique,
vol. 7 and 10.
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