A new system of chemical philosophy, Volume 2, Part 1Dalton, John
Science
A new system of chemical philosophy, Volume 2, Part 1
Dalton, John
Atomic theory; Chemistry, Inorganic
+-----------+---------------+-----------+
| Temp. by |Mean dilatation| Temp. by |
|copper rod | of platina |platina rod|
| Therm. | in volume. | Therm. |
+-----------+---------------+-----------+
| | | |
| 100° | ¹/₃₇₇₀₀ | 100° |
| 328.8 | ¹/₃₆₃₀₀ | 311.6 |
+-----------+---------------+-----------+
Connected with this subject was another important enquiry, whether
the capacities of bodies for heat remain constant at different
temperatures, or whether they diminish or increase as the temperature
advances. In other words, does a body that requires a certain quantity
of heat to raise it from 0° to 100° centigrade, require the same
quantity to raise it from 100° to 200°, and from 200 to 300°, &c.; or
does it require less or more as we ascend? This enquiry involves that
of the measure of temperature. They adopt the uniform expansion of air,
or the air thermometer, as the proper measure, and find the capacity of
iron,
From 0° to 100° = .1098
0 to 200 = .1150
0 to 300 = .1218
0 to 350 = .1255
the capacity of an equal weight of water being 1.
The following Table exhibits the capacities of seven other bodies
according to their results.
TABLE V.
+---------+--------------+--------------+
| |Mean capacity |Mean capacity |
| | between 0° | between 0° |
| | and 100° | and 300° |
+---------+--------------+--------------+
|Mercury | .0330 | .0350 |
|Zinc | .0927 | .1015 |
|Antimony | .0507 | .0549 |
|Silver | .0557 | .0611 |
|Copper | .0949 | .1013 |
|Platina | .0335 | .0355 |
|Glass | .1770 | .1900 |
+---------+--------------+--------------+
According to this table the capacities of bodies _increase_ with the
temperature in a small degree: and the increase, though it would still
exist, would be less, if the common mercurial thermometer were the
measure of temperature.
Also supposing that thermometers made of these bodies and graduated by
immersion in freezing and boiling water into 100°; if these were all
immersed in a fluid in which an air thermometer stood at 300°. Then the
relative temperatures of the several thermometers would be as under, if
measured by the absolute quantity of heat acquired, namely,
Iron 322.2°
Silver 329.3
Zinc 328.5
Antimony 324.8
Glass 322.1
Copper 320.0
Mercury 318.2
Platina 317.9
From these observations they infer that the law which has been
promulgated for the refrigeration of bodies, cannot be strictly true:
namely, that bodies part with heat in proportion as their temperature
exceeds that of the surrounding medium.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account