A new system of chemical philosophy, Volume 2, Part 1Dalton, John
Science
A new system of chemical philosophy, Volume 2, Part 1
Dalton, John
Atomic theory; Chemistry, Inorganic
3. _Phosphuretted hydrogen and hydrogen; also carburetted hydrogen and
hydrogen, and carburetted hydrogen and carbonic oxide._
The notation being as above, we have _x_ + _y_ = _w_, and 2_x_ + ½_y_ =
_g_ (see page 171): and,
2_g_ - _w_ 4_w_ - 2_g_
_x_ = -----------, and _y_ = -----------.
3 3
4. _Olefiant gas and carburetted hydrogen._
The notation being as above, we have
_x_ + _y_ = _w_, and
3_x_ + 2_y_ = _g_; whence
_x_ = _g_ - 2_w_ and
_y_ = 3_w_ - _g_.
5. _Carburetted hydrogen, carbonic oxide and hydrogen._
Let _x_ = carburetted hydrogen, _y_ = carbonic oxide, _z_ = the
hydrogen, _g_ = the oxygen spent in the combustion of _w_ volumes of
mixed gas, and _a_ = the carbonic acid produced.
Then _x_ + _y_ + _z_ = _w_,
_x_ + ½_y_ + ½_z_ = _g_,
and 2_x_ + _y_ = _a_.
whence we have
2_g_ - _w_ 3_a_ - 2_g_ + _w_
_x_ = -----------, _y_ = -----------------
3 3
and _z_ = _w_ - _a_.
6. _Olefiant gas, carburetted hydrogen and carbonic oxide._
Let _a_ = the olefiant gas, _y_ = the carburetted hydrogen, and _z_ =
equal the carbonic oxide, _g_ = the oxygen entering into combination,
and _a_ = the carbonic acid produced; also _w_ = the whole volume as
before.
Then we have _x_ + _y_ + _z_ = _w_,
3_x_ + 2_y_ + ½_z_ = _g_,
and 2_x_ + _y_ + _z_ = _a_.
Whence _x_ = _a_ - _w_,
_y_ = 4_w_ - 5_a_ + 2_g_
-------------------,
3
and _z_ = ⅔(_w_ + _a_ - _g_).
7. _Superolefiant gas,[29] carburetted hydrogen, and carbonic oxide._
[Footnote 29: A gas found in oil and coal gas. See Manchester Memoirs,
vol. 4 (new series), page 73.]
Let _x_ = volume of superolefiant, _y_ = volume of carburetted
hydrogen, _z_ = volume of carbonic oxide, _g_ = the oxygen combining,
_a_ = carbonic acid produced, and _w_ = volume of mixed gas.
Then _x_ + _y_ + _z_ = _w_,
4½_x_ + 2_y_ + ½_z_ = _g_,
and 3_x_ + _y_ + _z_ = _a_.
Whence _x_ = _a_ - _w_
----------,
2
_y_ = 3_w_ - 4_a_ + 2_g_
------------------,
3
and _z_ = 3_w_ - 4_g_ + 5_a_
-------------------.
6
8. _Superolefiant gas, carburetted hydrogen, carbonic oxide, and
hydrogen._
This is the mixture of gases obtained by a red heat from coal and oil,
after being freed from carbonic acid, &c., by the usual means.
This mixture requires a very complicated formula, in consequence of
the specific gravities of the gases entering into the calculus. The
importance of the subject however may be an apology for the labour.
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