A new system of chemical philosophy, Volume 2, Part 1Dalton, John
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A new system of chemical philosophy, Volume 2, Part 1
Dalton, John
Atomic theory; Chemistry, Inorganic
Two views of the nature of these bodies have been given in vol. 1,
(see pages 260, and 484, &c.). In the former they are considered as
simple metals; in the latter, as compound bodies resulting from the
abstraction of oxygen from the hydrates of potash and soda; or as being
constituted of 1 atom of hydrogen united to 1 atom of pure potash or
soda respectively. Those who have had the most experience on these
elements, Sir H. Davy, and M. M. Gay Lussac and Thenard, seem now to
concur in the former view, and it has been adopted by most chemists.
Part of the objections which we made to this view have been obviated,
it should seem, by establishing the fact, that oxymuriatic gas and
hydrogen gas united, form muriatic acid gas. There are still, however,
difficulties to remove before this view can be considered perfectly
satisfactory; but they are not greater perhaps than would attach
to any other explanation of the facts connected with the subject.
Besides potassium and sodium, experience as well as analogy would seem
to render probable, if not to establish, the existence of barium,
strontium, and calcium as metals, of which barytes, strontites, and
lime are the protoxides, as potash and soda are of the other two
metals; (other oxides of potassium and sodium are stated, see page
55-57); barium has a deutoxide, and probably calcium likewise. The
rest of the earths, as magnesia, alumine, silex, &c. are by analogy
considered by most chemists as oxides of particular metals, but the
proportions of their elements have not been determined.
ALUM.
At page 531, vol. 1, we have given the constitution of this important
salt, as under: since that time Mr. R. Phillips has announced another
view of it; and Dr. Thomson has published one differing from both of
these. They are as follow:
_Dalton_-- 1 atom sulphate of potash.
4 atoms sulphate of alumine.
30 atoms water.
_Phillips_-- 1 atom bisulphate of potash.
2 atoms sulphate of alumine.
22 atoms water.
_Thomson_-- 1 atom sulphate of potash.
3 atoms sulphate of alumine.
25 atoms water.
Notwithstanding these differences, there is a near approximation in all
three, in regard to the quantities of acid, alumine, potash, and water
in the salt. This is accounted for partly in the different relative
weights of the atoms, as estimated by the different analysts, but
chiefly in that of alumine.
Some very curious results occurred to me about 10 years ago in
analysing alum; they were new to me, but I have since found they had
been previously discovered by Scheele. (See his essay on silex, clay,
and alum, 1776.) As his observations are not to be found in any of our
elementary books that I have seen, I shall give the particulars of my
own experiments here.
Public-domain text, read in full here on John Shaqi.
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