A new system of chemical philosophy, Volume 2, Part 1Dalton, John
Science
A new system of chemical philosophy, Volume 2, Part 1
Dalton, John
Atomic theory; Chemistry, Inorganic
The green oxide being the most prominent compound next to the chromic
acid, being commonly produced from it by any deoxidizing process, being
the lowest oxide known, and combining with acids, is on these accounts
entitled to the consideration of the protoxide; indeed there does not
seem an instance where the protoxide of a metal is unknown, whilst the
deutoxide and compound oxides are known. There is however, another
oxide observed by Vauquelin and by Berzelius, which is obtained by
heating the nitrate, or combination of nitric acid and the green oxide,
to dryness and expelling the acid; this oxide is brown, and gives
oxymuriatic acid when treated with muriatic acid; on this account it
would seem to be intermediate between the green oxide and the chromic
acid; it is probably a combination of the two, or the _chromate of
chromium_. On the other view however, it must be considered as the
deutoxide. What corroborates the notion of the green oxide being 39, is
the fact which I have observed, of 46 parts of chromic acid combining
with 64 of the green oxide of iron to form 110 of chromate of iron; in
this combination the oxide of iron may be said to borrow 1 atom of
oxygen from the chromic acid, and the compound may then be considered
as the union of the green oxide of chrome, and the red oxide of iron.
When this precipitate is subjected to the action of muriatic acid, a
green solution is obtained containing the oxide of chrome, and red
oxide of iron is precipitated, as Vauquelin has observed. To form the
above chromate (or rather subchromate) of iron, let a given portion
of neutral chromate of potash be treated with green sulphate of iron,
and lime water be added, sufficient to saturate the sulphuric acid, a
brown red precipitate is obtained; more sulphate and lime water must be
gradually added to the clear liquid till the precipitate become green,
when the proportions will be found as above stated. This artificial
compound seems a subchromate; whereas the native compound seems to be a
chromate. That there is some uncertainty in decomposing a chromate by
heat with a view to obtain the green oxide, I have reason to suspect
from having decomposed 5⅓ grains of chromate of mercury by a moderate
red heat; this compound contained 1.1 chromic acid, and it yielded only
.6 of green oxide, whereas it should have been .9 or .8 at least.
Upon the whole I think the evidence is in favour of the opinion that
the atom of chrome is 32, the green or protoxide 39, and the deutoxide
or chromic acid is 46.
24. _Oxides of uranium._
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