A new system of chemical philosophy, Volume 2, Part 1Dalton, John
Science
A new system of chemical philosophy, Volume 2, Part 1
Dalton, John
Atomic theory; Chemistry, Inorganic
There appear to be two oxides of uranium from the experiments of
Klaproth, Bucholz, and Vauquelin; but the proportions of metal and
oxygen have not been very nearly ascertained, from the great scarcity
of the minerals containing this metal. (Vid. Bucholz, An. de Chimie,
56--142. Vauquelin, ibid. 68--277; or Nicholson’s Journ. 25--69). The
oxides are obtained by precipitation from solutions of the minerals
in the nitric or muriatic acid, the foreign substances being first
separated.
The protoxide of uranium precipitates dark bottle green by caustic
alkalies, and forms crystallizable salts with acids; the other,
probably the deutoxide, precipitates orange yellow, and forms
uncrystallizable salts with acids; in these respects the oxides bear a
near resemblance to those of iron.
Bucholz estimates the yellow oxide at 100 metal + from 25 to 32 oxygen;
as it yields oxymuriatic acid when treated with muriatic, it is most
likely to be the deutoxide; now if we take 28 for the oxygen combined
with 100 metal, the protoxide must consist of 100 metal + 14 oxygen, or
of 50 metal + 7 oxygen, and the atom of uranium = 50. From his account
of the sulphate and nitrate of uranium the weight of the atom might be
inferred to be double of the above or 100. These different conclusions
can only be elucidated by future experiments.
25. _Oxides of molybdenum._
The latest and as it should seem most accurate experiments on
the oxides of molybdenum were made by Bucholz. (Vid. Nicholson’s
Journal, 20, p. 121). There appear to be 3 oxides or combinations
of molybdenum and oxygen, namely, the _brown_, the _blue_, and the
_white_ or _yellow_. The two last have the character of acids, and
none of them seem to form salts with acids, like oxides in general.
Bucholz ascertained the above gradation, and that the white oxide or
molybdic acid contains ⅓ of its weight of oxygen; (which has since
been corroborated by Berzelius); he also found that the blue was best
formed by mixing, triturating, and boiling in water 3 parts of brown
oxide, and 4 of white, or one of metal, and two of acid; and that it
has acid qualities as well as the white. Bucholz also found 3 parts
of liquid ammonia of the sp. gr. .97 dissolve 1 of molybdic acid; now
3 parts of ammonia = .186 real (VOL. 1, p. 422); and 1 ∶ .186 ∷ 64 ∶
12, the quantity of ammonia usually saturated by one atom of acid;
and Berzelius found 100 molybdic acid saturate 155 oxide of lead, or
63 acid to 97 oxide. The native sulphuret of molybdenum (the state in
which this metal is usually found) was analyzed by Bucholz and found to
consist of 60 metal and 40 sulphur.
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