A new system of chemical philosophy, Volume 2, Part 1Dalton, John
Science
A new system of chemical philosophy, Volume 2, Part 1
Dalton, John
Atomic theory; Chemistry, Inorganic
barytes and 82 sulphur.
_Hydrosulphuret of barytes._ This compound may be formed in the same
manner as that of lime, and is found to have similar properties. The
proportions for mutual saturation are, I find, as in the case of lime,
15 sulphuretted hydrogen to 68 barytes by weight, or one atom of each.
4. _Sulphurets of strontites._
The protosulphuret and quadrisulphuret of strontites may be formed
in the same way as those of lime and barytes. From a few experiments
made on these compounds I have not observed any remarkable feature of
distinction between them and the corresponding ones of the other earths.
_Hydrosulphuret of strontites._ This compound may be formed in the same
way as that of lime; the proportions to produce mutual saturation will
be 1 atom of each, or 15 parts sulphuretted hydrogen, to 46 strontites
by weight.
5, 6, 7, 8, _and_ 9. _Sulphurets of alumine, silex, yttria, glucine_,
and _zircone_.
I made several unsuccessful attempts to combine alumine and sulphur.
When alumine and sulphur mixed together are heated, the sulphur
sublimes chiefly, and leaves the alumine with traces of sulphate of
alumine.
In the humid way, recently precipitated and moist alumine mixed
with sulphur and boiled in water, give a liquid with some traces of
sulphuric acid, but no sulphuret of alumine; the sulphur and alumine
both subside, and when the sulphur is either sublimed or burnt, the
alumine remains much the same as at first. When a solution of alum
is treated with sulphuret of lime, sulphate of lime is precipitated
along with the greatest part of the sulphur in a kind of feeble union
rather than mechanical mixture, it should seem; the alumine is at the
same time precipitated probably in mechanical mixture; there remain in
solution a little sulphuret of potash and sulphate of lime.
_Sulphuret of silex_ is not known, I apprehend, to exist. When
silicated potash in solution is treated with quadrisulphuret of lime, a
copious dark brown or black precipitate instantly appears; the liquid
when filtered is of a pale yellow colour, and seems to contain about
one half of the sulphur and potash, whilst the other half is thrown
down in union with the lime and silex. This black compound is probably
1 atom of lime, 2 of sulphur, 2 of potash, and 2 of silex; it cannot
therefore be accounted a sulphuret of silex.
_Sulphurets of yttria_, _glucine_, and _zircone_, are as yet, I
presume, unknown.
10. _Sulphurets of potash._
Potash has a strong affinity for sulphur and unites with it in various
ways and proportions.
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