A new system of chemical philosophy, Volume 2, Part 1Dalton, John
Science
A new system of chemical philosophy, Volume 2, Part 1
Dalton, John
Atomic theory; Chemistry, Inorganic
1st. _Sulphuretted carbonate of potash._ This consists of 1 atom
carbonate of potash (61) with 1 atom of sulphur (14). Its analysis
may be effected as follows: the quantity of carbonic acid may be
found by the lime water necessary to saturate it; the potash may be
known from the quantity previously entering into the mixture; and
the sulphur in the same manner, or from the quantity of sulphuretted
carbonate of lead that it forms.--The sulphur may also be known, from
the quantity of oxygen it requires by means of oxymuriate of lime to
produce saturation; this I find to take place when the oxygen is half
the weight of the sulphur, or one atom to one of sulphur; it soon
happens, that one atom of sulphur deprives two others of their oxygen,
and sulphuric acid is formed whilst the other two atoms of sulphur join
the carbonate of lime and are precipitated along with it. As it may
frequently happen, that the sulphuretted carbonate is mixed with common
carbonate of potash, the proportions may be found by means of nitrate
of lead, which being cautiously dropped into the solution, lets fall
first the brown sulphuretted carbonate of lead, and then the common
white carbonate of lead.
The sulphuretted carbonate of potash absorbs oxygen and precipitates
metals much the same in appearance as the other sulphurets; but
essential distinctions are observable, some of which are noticed above,
and others will appear in the sequel.
2 and 3. The _trisulphuret_ and _quadrisulphuret_ of potash so nearly
resemble the quadrisulphuret of lime in their properties, as not to
require any additional remarks.
_Hydrosulphuret of potash._ This combination, when duly proportioned,
consists of 15 parts sulphuretted hydrogen, and 42 potash by weight,
or one atom of each. It may be formed by directly uniting the two
elements, or by decomposing hydrosulphuret of lime by carbonate of
potash. Its properties agree with those of the other hydrosulphurets.
11. _Sulphurets of soda._
I have repeated most of the experiments on the sulphurization of potash
with soda, and have not found anyone remarkable feature of distinction,
besides those which arise from the weights of the atoms.
1. _Sulphuretted carbonate of soda_ consists of 1 atom of carbonate of
soda united to 1 of sulphur; or of 47 parts of the former and 14 of the
latter.
2. _Trisulphuret of soda_ consists of 1 atom soda (28) and 3 of sulphur
(42).
3. _Quadrisulphuret of soda_ consists of 1 atom soda (28) and 4 atoms
of sulphur (56).
_Hydrosulphuret of soda._ This compound consists of one atom of each
of the elements, or 15 sulphuretted hydrogen, and 28 soda. In other
respects it agrees with hydrosulphuret of potash.
12. _Sulphuret of ammonia._
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