A new system of chemical philosophy, Volume 2, Part 1Dalton, John
Science
A new system of chemical philosophy, Volume 2, Part 1
Dalton, John
Atomic theory; Chemistry, Inorganic
I have obtained the sulphuret of platina in five ways: 1st. By pouring
sulphuret of lime solution by degrees into muriate of platina, and
agitating the mixture well or till it grew black each time; after
digesting for some days, repeated filtering, and drying, a black
powder is obtained: 2. Instead of sulphuret, hydrosulphuret of lime
was used; the precipitate was obtained under like circumstances: 3d.
Sulphuretted hydrogen water was used, and the precipitate obtained
in like manner: 4th. Ten grains of ammonia-muriate of platina were
treated with sulphuretted hydrogen water; by continued agitation the
yellow powder disappeared, the liquid looked uniformly black, and at
length a precipitate was formed; by repeated filtration and addition of
sulphuretted hydrogen water, the whole of the platina was thrown down,
and the liquid remained colourless; but it is difficult to discover the
exact quantity of sulphuretted hydrogen requisite for any weight of the
ammonia-muriate from the tediousness of the operation; 6 grains of well
dried black powder were obtained, besides perhaps 1 grain of loss on
the filters: 5th. Ammonia-muriate of platina was heated in a covered
crucible along with sulphur till it was judged that all the uncombined
sulphur was sublimed or dissipated.
All these sulphurets appear to me to be the same when dried in a
moderate heat. When exposed to a low red heat they yield water and
sulphurous acid, and lose about ⅖ of their weight.
The subject however, requires further investigation. The sulphurets
of platina appear of a complex nature, and the proportions of their
elements are not yet determined with precision.
15. _Sulphurets of silver._
Silver combines with sulphur in two different proportions, and forms
two sulphurets, both of them black or dark brown.
1. _Protosulphuret of silver._ This may be formed either by the dry
or humid way: if thin lamina of silver be heated with sulphur, they
combine and form this sulphuret; a higher degree of heat expels the
sulphur again. It is formed too by passing sulphuretted hydrogen or a
hydrosulphuret through a solution of silver in nitric or other acids.
The atom of silver unites with that of sulphur, whilst the hydrogen
unites with the oxygen. Of course this compound is composed of 90
silver, and 14 sulphur, and the atom weighs 104; or 100 silver unite
with 15.5 sulphur. Klaproth finds 100 silver and 17.6 sulphur; Wenzel
100 silver, and 14.7 sulphur; Berzelius 100 silver, and 14.9 sulphur;
and Vauquelin 100 silver, and 14 sulphur.
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