A new system of chemical philosophy, Volume 2, Part 1Dalton, John
Science
A new system of chemical philosophy, Volume 2, Part 1
Dalton, John
Atomic theory; Chemistry, Inorganic
_Hydrosulphuret._ When antimony is precipitated from a solution, by
sulphuretted hydrogen or a hydrosulphuret, or from an alkaline solution
of the sulphuret by an acid, it appears in the form of an orange yellow
powder, denominated golden sulphuret. It is constituted of 1 atom
sulphuretted hydrogen and 1 of protoxide of antimony; it readily yields
sulphuretted hydrogen by muriatic acid, and the oxide combines with
this acid. Exposed to heat, water is expelled and protosulphuret left.
It is constituted of 40 antimony, 7 oxygen, 14 sulphur and 1 hydrogen;
or of 54 protosulphuret and 8 water.
_Bisulphuretted_, _trisulphuretted_ and _quadrisulphuretted oxide of
antimony_. When crystallized muriate of antimony is agitated along with
dilute quadrisulphuret of lime, an orange yellow compound is formed,
consisting of the oxide and sulphur. To 350 quadrisulphuret of lime,
diluted with lime water, I put 22 grains moist crystals of muriate, and
agitated well for some time. Got 26 grains dry yellow sulphuret, which
heated burned blue, and left from 13 to 14 black grey sulphuret, equal
to 10 antimony nearly; hence it must have been a quadrisulphuret, or
rather sulphuretted oxide; for, by heating this compound in muriatic
acid, a solution is obtained and sulphur liberated without the
extrication of gas. Less of the sulphuret of lime would have produced a
sulphuret of the same colour, but containing less of sulphur; so that
it is evident various proportions may exist in combination. Instead of
the crystallized muriate, the recently precipitated oxide, nearly free
from acid, may be used to produce these compounds.
31. _Sulphuret of tellurium._
Tellurium unites with nearly its weight of sulphur, by heat, according
to Davy. It is probable that as usual in such cases, a protosulphuret
is formed. This would lead to the conclusion that the atom of tellurium
is only equal in weight to that of sulphur; which does not accord with
results from the other combinations of tellurium, and hence the above
fact may not perhaps be sufficiently ascertained.
32. _Sulphurets of arsenic._
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