A new system of chemical philosophy, Volume 2, Part 1Dalton, John
Science
A new system of chemical philosophy, Volume 2, Part 1
Dalton, John
Atomic theory; Chemistry, Inorganic
_Deutosulphuret_, _trisulphuret_ and _quadrisulphuret_. These may be
formed by treating neutral solutions of manganese, or the recently
precipitated oxide, by quadrisulphuret of lime. They are formed
somewhat slowly and by considerable agitation with a smaller or greater
proportion of the lime sulphuret. They are all light drab, and are
reduced to the protosulphuret by heat.
35. _Sulphuret of chromium._
I have not had an opportunity of ascertaining whether chromium or its
oxides combine with sulphur or not, though several attempts were made
for that purpose.
36. _Sulphuret of uranium_.
From the experiments of Bucholz it would seem that uranium may be
combined with sulphur, but the proportions have not been ascertained.
(An. de Chimie. 56--142.)
37. _Sulphuret of molybdenum._
From Bucholz and Klaproth’s analyses of molybdena it would seem that
the native sulphuret consists of 60 metal and 40 sulphur; but it does
not appear whether this should be considered as the protosulphuret or
the deutosulphuret. If it is the protosulphuret the atom of molybdenum
weighs 21, but if the deutosulphuret, the atom of metal weighs 42; and
the atom of the sulphuret or molybdena must weigh either 35 or 70.
38. _Sulphuret of tungsten._
According to Berzelius, a sulphuret of tungsten may be obtained, by
heating a mixture of tungstic acid and sulphuret of mercury in the
proportion of 1 to 4, in a crucible. The mixture in his experiment was
covered with charcoal and the crucible inclosed in another containing
charcoal; the whole was then exposed to the heat of a furnace for half
an hour. The sulphuret obtained was a greyish black powder; it was
found to consist of 100 metal and 33¼ sulphur, or about 3 metal to 1
sulphur. Hence this must be the deutosulphuret if we consider the atom
of tungsten to be 84; but considering the high degree of heat to which
it was exposed, it would seem more likely to be the protosulphuret; if
so, the atom of tungsten must be considered as 42 only, or half of the
other number.
39. _Sulphuret of titanium._
No compound of titanium and sulphur has been formed.
40. _Sulphuret of columbium._
This combination is unknown.
41. _Sulphuret of cerium._
This combination is also unknown.
SECTION 15.
EARTHY, ALKALINE, METALLIC AND OTHER PHOSPHURETS.
Phosphorus like sulphur is capable of being combined with several of
the earths and metals as well as with other bodies; but the combination
is not so easily effected, and the products are less interesting
than those of sulphur: from considerations of these circumstances
together with those of the expence and danger in making experiments
on phosphorus we may account for, this class of bodies being as yet
imperfectly known.
Margraf in 1740 attempted to combine phosphorus with many of the
metals; but his experiments were mostly unsuccessful.
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