A new system of chemical philosophy, Volume 2, Part 1Dalton, John
Science
A new system of chemical philosophy, Volume 2, Part 1
Dalton, John
Atomic theory; Chemistry, Inorganic
The quantity of oxygen necessary to saturate a given volume of
phosphuretted hydrogen is easily found. Oxygen gas containing a known
per centage of azotic gas, must be used in some excess, mixed with a
due portion of the gas. After exploding the mixture, the loss must be
observed, and then the remaining oxygen must be found by exploding
it with hydrogen. Hence the true volume of oxygen spent by the first
explosion, and that of the combustible gas are both determined. The
due proportion of oxygen is so nearly 2 to 1, that I have not been
able to determine on which side the truth lies. Dr. Thomson says that
when phosphuretted hydrogen and oxygen are mixed, two volumes to one,
a white smoke takes place, the volume of oxygen gradually disappears,
and there remains behind a quantity of hydrogen exactly equal to the
original volume of the phosphuretted hydrogen. I have observed nothing
at all like this. A mixture of phosphuretted hydrogen and oxygen stood
24 hours without sensible diminution, and afterwards being exploded, 2
volumes of oxygen disappeared for 1 of phosphuretted hydrogen, the same
as would have done at the moment of mixing. Perhaps the _temperature_
may have some influence; mine was about 55°.
I have tried the minimum of oxygen that will consume or dissipate
phosphuretted hydrogen gas. It may be exploded with about ¼ of its
volume of oxygen, with the same phenomena as Davy observed of the
hydrophosphoric gas. Phosphorus is thrown down and a volume of
combustible gas is left about 10 per cent. greater than the original
volume of phosphuretted hydrogen. This gas is nearly pure hydrogen.
Hence the whole gas may be dissipated at 2 successive explosions, by
rather less than an equal volume of oxygen. If phosphuretted hydrogen
be exploded with an equal volume of oxygen, phosphorous acid, water and
a little phosphoric acid are formed, and some hydrogen remains.
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