A new system of chemical philosophy, Volume 2, Part 1Dalton, John
Science
A new system of chemical philosophy, Volume 2, Part 1
Dalton, John
Atomic theory; Chemistry, Inorganic
It may be proper to advert more particularly to the hydrophosphoric gas
of Davy. That this gas is the same as that we have been describing,
can hardly admit of a doubt. Their near agreement in sp. gr., in
their absorbability by water, in the quantity of oxygen requisite
for their combustion, in their moderate expansion by burning with a
minimum of oxygen and in their combustibility by oxymuriatic acid, are
circumstances sufficient to warrant their identity. It is said that
by heating potassium in this gas, one volume yields two of hydrogen;
but it has not been found to yield two volumes by electricity, the
more accurate criterion. Besides, both Davy and Gay Lussac find that
potassium heated in the more common phosphuretted hydrogen expands
it from 1 to 1⅓ or 1½ volume, which common electricity will not do;
it is presumed therefore that the potassium in some way conduces to
the production of a portion of the hydrogen. Spontaneous ignition
or explosion is, I believe, no distinctive mark of variety in
phosphuretted hydrogen; when this gas is _produced_, it is usually
explosive from the uncombined phosphorus which it elevates; but the
best and purest phosphuretted hydrogen loses the property wholly or
partially by standing a while over water, though it loses no sensible
part of its phosphorus.
It is commonly stated that phosphuretted hydrogen deposits phosphorus
by long standing. This seems to be true; but the deposition is slower
than I imagined. Seven years ago I set aside a bottle of impure
phosphuretted hydrogen which I then labeled, 10 combustible take
14.6 oxygen; this bottle has not been preserved with special care to
seclude the atmosphere; notwithstanding that, it is now such, that 10
combustible take 6.7 oxygen, and hence it still contains some genuine
phosphuretted hydrogen.
2 _and_ 3. _Phosphurets of carbone and sulphur._
See VOL. 1. page 464.
_4. Phosphuret of lime._
This compound may be formed by subliming phosphorus in a glass tube
containing small fragments of recently calcined lime, heated to a low
red. The sublimed phosphorus coming into contact with the hot lime,
the two unite with a vivid glow, and in due time mutual saturation is
produced. The result is a dry, hard compound of a deep brown or reddish
colour, which on cooling must be put into a bottle and well corked, if
not intended for immediate use, as it soon changes by the action of
atmospheric air and moisture. With this precaution, I have reason to
think it may be kept unimpaired for years.
As far as I know, no experiments have been published relating to the
proportion in which phosphorus and lime unite. M. Dulong, in a valuable
paper on the combinations of phosphorus and oxygen, in the _Memoires de
la Société d’Arcueil_, VOL. 3. (1817,) has given some account of his
experiments on the earthy phosphurets; but it is to be regretted that
he has given none on the proportions of their elements.
Public-domain text, read in full here on John Shaqi.
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