A new system of chemical philosophy, Volume 2, Part 1Dalton, John
Science
A new system of chemical philosophy, Volume 2, Part 1
Dalton, John
Atomic theory; Chemistry, Inorganic
According to Dulong, when the earthy phosphurets are decomposed by
water, phosphuretted hydrogen and subphosphorous acid are formed. I
believe this determination is right; for I find at most only ⅓ of the
above proportion of phosphorus in the phosphuretted hydrogen yielded
by 10 grains of the phosphuret of lime; the remaining ⅔ seem to rest
in the liquid in combination with the oxygen and lime; that is, 1 atom
of hydrogen combines with 1 of phosphorus, and 1 of oxygen with 2 of
phosphorus. Notwithstanding this, the phosphoric acid produced from the
residue by means of oxymuriate of lime, does not in general correspond
to the above quantity. Perhaps this loss may be owing to the phosphorus
carried over in mechanical suspension by the gas.
M. Dulong observes, that even the earthy subphosphites are very
soluble; this did not appear to me to be the case with that of lime: 10
grains of phosphate of lime, that had been exposed for 20 minutes to
the air, were put into a gas bottle filled with 400 grains of water;
this was kept at nearly the boiling heat for an hour, when 725 grain
measures of gas were produced, and some phosphorus was carried over
with it into the receiving bottle and bason of water. The gas being
analysed, was found to consist of 62 per cent. phosphuretted hydrogen,
33 hydrogen and 5 common air. The 400 grains of water in the gas bottle
treated with oxymuriate of lime, and then with lime water, scarcely
gave any appreciable quantity of phosphate of lime. The insoluble
residue when dried yielded 9 grains. This dissolved in muriatic acid
left a fraction of a grain of dirty yellow powder, which indicated some
phosphorus; and the muriate of lime indicated about 6 grains of lime.
_5. Phosphuret of barytes._
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