A Practical Manual of the Collodion Process, Giving in Detail a Method For Producing Positive and Negative Pictures on Glass and Paper.Humphrey, S. D. (Samuel Dwight)
Science
A Practical Manual of the Collodion Process, Giving in Detail a Method For Producing Positive and Negative Pictures on Glass and Paper.
Humphrey, S. D. (Samuel Dwight)
Ambrotype; Photography
_Properties._--Perchloride of iron may be obtained in the solid form by
heating iron wire in excess of chlorine; it condenses in the shape of
brilliant and iridescent brown crystals, which are volatile, and dissolve
in water, the solution being acid to test-paper. It is also soluble in
alcohol, forming the _tinctura ferri sesquichloridi_ of the Pharmacopoeia.
Commercial perchloride of iron ordinarily contains an excess of
hydrochloric acid.
Litmus.
Litmus is a vegetable substance, prepared from various _lichens_, which
are principally collected on rocks adjoining the sea. The coloring matter
is extracted by a peculiar process, and afterwards made up into a paste
with chalk, plaster of Paris, &c.
Litmus occurs in commerce in the form of small cubes, of a fine violet
color. In using it for the preparation of test-papers, it is digested
in hot water, and sheets of porous paper are soaked in the blue liquid
so formed. The red papers are prepared at first in the same manner, but
afterwards placed in water which has been rendered faintly acid with
sulphuric or hydrochloric acid.
Mercury, Bichloride of.
Symbol, HgCl{2}. Atomic weight, 274.
This salt, also called corrosive sublimate, and sometimes _chloride of
mercury_ (the atomic weight of mercury being halved), may be formed by
heating mercury in excess of chlorine, or, more economically, by subliming
a mixture of persulphate of mercury and chloride of sodium.
_Properties._--a very corrosive and poisonous salt, usually sold in
semi-transparent, crystalline masses, or in the state of powder. Soluble
in 16 parts of cold, and in 3 of hot water; more abundantly so in alcohol,
and also in ether. The solubility in water may be increased almost to any
extent by the addition of free hydrochloric acid.
The protochloride of mercury is an insoluble white powder, commonly known
under the name of _calomel_.
Milk.
The milk of herbivorous animals contains three principal
constituents--fatty matter, caseine, and sugar; in addition to these,
small quantities of the chloride of potassium, and of phosphates of lime
and magnesia, are present.
The fatty matter is contained in small cells, and forms the greater part
of the cream which rises to the surface of the milk on standing. Hence
_skimmed_ milk is to be preferred for photographic use.
The second constituent, _caseine_, is an organic principle somewhat
analogous to albumen in composition and properties. Its aqueous solution
however does not, like albumen, _coagulate_ on boiling, unless _an acid_
be present, which probably removes a small portion of alkali with which
the caseine was previously combined. The substance termed "rennet," which
is the dried stomach of the calf, possesses the property of coagulating
caseine, but the exact mode of its action is unknown. Sherry wine is also
employed to curdle milk; but brandy and other spirituous liquids, when
free from acid and astringent matter, have no effect.
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