A Practical Manual of the Collodion Process, Giving in Detail a Method For Producing Positive and Negative Pictures on Glass and Paper.Humphrey, S. D. (Samuel Dwight)
Science
A Practical Manual of the Collodion Process, Giving in Detail a Method For Producing Positive and Negative Pictures on Glass and Paper.
Humphrey, S. D. (Samuel Dwight)
Ambrotype; Photography
In all these cases a proportion of the caseine usually remains in a
soluble form in the _whey_; but when the milk is coagulated by the
addition of acids, the quantity so left is very small, and hence the
use of the rennet is to be preferred, since the presence of caseine
facilitates the reduction of the sensitive silver salts.
Caseine combines with oxide of silver in the same manner as albumen,
forming a white coagulum, which becomes _brick-red_ on exposure to light.
Sugar of milk, the third principal constituent, differs from both
cane and grape sugar; it may be obtained by evaporating _whey_ until
crystallization begins to take place. It is hard and gritty, and only
slightly sweet; slowly soluble, without forming a syrup, in about two and
a half parts of boiling, and six of cold water. It does not ferment and
form alcohol on the addition of yeast, like grape sugar, but by the action
of _decomposing animal matter_ is converted into lactic acid.
When skimmed milk is exposed to the air for some hours it gradually
becomes _sour_, from lactic acid formed in this way; and if then heated to
ebullition, the caseine coagulates very perfectly.
Nitric Acid.
Symbol, NO{5}. Atomic weight, 54.
Nitric acid, or _aqua-fortis_, is prepared by adding sulphuric acid
to nitrate of potash, and distilling the mixture in a retort. Sulphate
of potash and free nitric acid are formed, the latter of which, being
volatile, distils over in combination with one atom of water previously
united with sulphuric acid.
_Properties._--Anhydrous nitric acid is a solid substance, white and
crystalline, but it cannot be prepared except by an expensive and
complicated process.
The concentrated liquid nitric acid contains 1 atom of water, and has a
sp. gr. of about 1·5: if perfectly pure it is colorless, but usually it
has a slight yellow tint, from partial decomposition into peroxide of
nitrogen: it fumes strongly in the air.
The strength of commercial nitric acid is subject to much variation. An
acid of sp. gr. 1·42, containing about 4 atoms of water, is commonly
met with. If the specific gravity is much lower than this (less than
1·36), it will scarcely be adapted for the preparation of peroxyline.
The yellow _nitrous acid_, so called, is a strong nitric acid partially
saturated with the brown vapors of peroxide of nitrogen; it has a high
specific gravity, but this is somewhat deceptive, being caused in part
by the presence of the peroxide. On mixing with sulphuric acid the color
disappears, a compound being formed which has been termed a _sulphate of
nitrous acid_.
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