A Practical Manual of the Collodion Process, Giving in Detail a Method For Producing Positive and Negative Pictures on Glass and Paper.Humphrey, S. D. (Samuel Dwight)
Science
A Practical Manual of the Collodion Process, Giving in Detail a Method For Producing Positive and Negative Pictures on Glass and Paper.
Humphrey, S. D. (Samuel Dwight)
Ambrotype; Photography
Although termed an _acid_, this substance is strictly _neutral_; it does
not redden litmus-paper, and forms no salts. The addition of potash
or soda decomposes pyrogallic acid, at the same time increasing the
attraction for oxygen; hence this mixture may conveniently be employed for
absorbing the oxygen contained in atmospheric air. The compounds of silver
and gold are reduced by pyrogallic acid even more rapidly than by gallic
acid, the reducing agent absorbing the oxygen, and becoming converted into
carbonic acid and a brown matter insoluble in water.
Commercial pyrogallic acid is often contaminated with empyreumatic oil,
and also with a black insoluble substance known as _metagallic acid_,
which is formed when the heat is raised above the proper temperature in
the process of manufacture.
Sel D'or. (_See_ Gold, Hyposulphite of.)
Silver.
Symbol, Ag. Atomic Weight, 108.
This metal, the _luna_ or _diana_ of the alchemists, is found native in
Peru and Mexico; it occurs also in the form of sulphuret of silver.
When pure it has a sp. gr. of 10·5, and is very malleable and ductile;
melts at a bright red heat. Silver does not oxidize in the air, but
when exposed to an impure atmosphere containing traces of sulphuretted
hydrogen, it is slowly tarnished from formation of sulphuret of silver. It
dissolves in sulphuric acid, but the best solvent is nitric acid.
The standard coin of the realm is an alloy of silver and copper,
containing about one-eleventh of the latter metal. It may be converted
into nitrate of silver, sufficiently pure for photographic purposes,
by dissolving it in nitric acid and evaporating the solution to the
crystallizing point: or, if the quantity be small, the solution may be
boiled down to complete dryness, and the residue _fused_ strongly; which
decomposes the nitrate of copper, but leaves the greater portion of the
silver salt unaffected. (N. B. Nitrate of silver which has undergone
fusion contains nitrite of silver, and will require the addition of acetic
acid if used for preparing the collodion sensitive film.)
Silver, Ammonio-Nitrate of.
Crystallized nitrate of silver absorbs ammoniacal gas rapidly, with
production of heat sufficient to fuse the resulting compound, which
is white, and consists of 100 parts of the nitrate + 29·5 of ammonia.
The compound however which photographers employ under the name of
ammonio-nitrate of silver, may be viewed more simply as a solution of the
oxide of silver in ammonia, without reference to the nitrate of ammonia
necessarily produced in the reaction.
Public-domain text, read in full here on John Shaqi.
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