A Practical Manual of the Collodion Process, Giving in Detail a Method For Producing Positive and Negative Pictures on Glass and Paper.Humphrey, S. D. (Samuel Dwight)
Science
A Practical Manual of the Collodion Process, Giving in Detail a Method For Producing Positive and Negative Pictures on Glass and Paper.
Humphrey, S. D. (Samuel Dwight)
Ambrotype; Photography
_Properties._--Usually met with in the form of solid lumps, or in
cylindrical sticks, which are formed by melting the potash and running
it into a mould. It always contain some atoms of water, which cannot be
driven off by the application of heat.
Potash is soluble almost to any extent in water, much heat being evolved.
The solution is powerfully alkaline and acts rapidly upon the skin; it
dissolves fatty and resinous bodies, converting them into soaps; Solution
of potash absorbs carbonic acid quickly from the air, and should therefore
be preserved in stoppered bottles; the glass stoppers must be wiped
occasionally, in order to prevent them from becoming immovably fixed by
the solvent action of the potash upon the silica of the glass.
The liquor potassæ of the London Pharmacopoeia has a sp. gr. of 1·063,
and contains about 5 per cent; of real potash. It is usually contaminated
with _carbonate_ of potash, which causes it to effervesce on the addition
of acids; also, to a less extent, with sulphate of potash, chloride of
potassium, silica, etc.
Potash, Carbonate of.
Symbol, KO CO{2}. Atomic weight, 70.
The impure carbonate of potash, termed _pearlash_, is obtained from the
ashes of wood and vegetable matter, in the same manner as carbonate of
soda is prepared from the ashes of seaweeds. Salts of potash and of soda
appear essential to vegetation, and are absorbed and approximated by
the living tissues of the plant. They exist in the vegetable structure
combined with organic acids in the form of salts, like the oxalate,
tartrate, etc., which when burned are converted into carbonates.
_Properties._--The pearlash of commerce contains large and variable
quantities of chloride of potassium, sulphate of potash, etc. A purer
carbonate is sold, which is free from sulphates, and with only a trace of
chlorides. Carbonate of potash is a strongly alkaline salt, deliquescent,
and soluble in twice its weight of cold water; insoluble in alcohol, and
employed to deprive it of water.
Pyrogallic Acid.
Symbol, C{8}H{4}O{4} (Stenhouse). Atomic weight. 84.
The term _pyro_ prefixed to gallic acid implies that the new substance is
obtained by the _action of heat_ upon that body. At a temperature of about
410° Fahr., gallic acid is decomposed, and a white sublimate forms, which
condenses in lamellar Crystals; this is pyrogallic acid.
Pyrogallic acid is very soluble in cold water, and in alcohol and ether;
the solution decomposes and becomes brown by exposure to the air. It gives
an indigo blue color with protosulphate of iron, which changes to dark
green if any persulphate be present.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account