A Practical Manual of the Collodion Process, Giving in Detail a Method For Producing Positive and Negative Pictures on Glass and Paper.Humphrey, S. D. (Samuel Dwight)
Science
A Practical Manual of the Collodion Process, Giving in Detail a Method For Producing Positive and Negative Pictures on Glass and Paper.
Humphrey, S. D. (Samuel Dwight)
Ambrotype; Photography
"Dissolve the hyposulphite of soda in four ounces of the water, the
chloride of gold in three ounces, the nitrate of silver in the remaining
ounce; then pour the diluted chloride by degrees into the hyposulphite,
stirring meanwhile with a glass rod; and afterwards the nitrate of silver
in the same way. This order of mixing the solution is to be strictly
observed; if it were reversed, the hyposulphite of soda being added to
the chloride of gold, the result would be the reduction of metallic gold.
The difference depends upon the fact that the hyposulphite of gold which
is formed is an exceedingly unstable substance, and cannot exist in
contact with unaltered chloride of gold. It is necessary that it should be
dissolved by hyposulphite of soda _immediately_ on its formation, and so
rendered more permanent by conversion into a double salt of soda and gold.
"The _time of coloration_ depends much upon the quantity of gold present,
and may in some cases be extended to many hours. The results of a few
experiments, performed roughly, appeared to indicate that the activity
of this bath is less affected by depression of temperature than those
prepared with tetrathionate. Certainly the injurious effects of prolonged
immersion are not so evident as with the first two formulæ: the purity of
the whites remains unaltered for many hours if the bath is new, but with
an old bath there is a tendency to yellowness, which is probably caused
by the presence of sulphuretted hydrogen. Fresh chloride of gold must be
added from time to time, as it appears to be required."
After the impression has remained in the toning bath a sufficient length
of time, it should be placed in a dish or sink of clean water, which
should be changed several times--floating for at least 12 hours; then it
may be taken out and hung up to dry.
"Touching."--The _coloring_ of a photograph forms no part of my process:
this is a matter to be given into the hands of an artist, and when it
bears the finishing touch of his skill, it is no longer a _photograph_,
but _an oil_ or _watercolor painting_; all the delicate workings of nature
having been lost or hidden under the colors.
A photograph may often be "touched" to advantage. If, as is frequently the
case, there be little white spots on the face of the paper, they may be
readily covered by the application of a little India ink, with the point
of a wet pencil or fine small brush.
Mounting of Positives.
This, though a small matter in itself, is worthy of great attention. The
durability of the proof depends much upon the purity of the paste used in
causing its adhesion to the Bristol board. I have employed the following
composition with the most eminent success:--
Public-domain text, read in full here on John Shaqi.
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