A practical treatise on the manufacture of perfumery : $b comprising directions for making all kinds of perfumes, sachet powders, fumigating materials, dentrifices, cosmetics, etc., etc., with a full account of the volatile oils, balsams, resins, and other natural and artificial perfume-substances, including the manufacture of fruit ethers, and tests of their purityDeite, C. (Carl)
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A practical treatise on the manufacture of perfumery : $b comprising directions for making all kinds of perfumes, sachet powders, fumigating materials, dentrifices, cosmetics, etc., etc., with a full account of the volatile oils, balsams, resins, and other natural and artificial perfume-substances, including the manufacture of fruit ethers, and tests of their purity
Deite, C. (Carl)
Cosmetics; Perfumes; Perfumes industry
Nitrobenzol is frequently adulterated with spirit of wine, which is
recognized by shaking the oil with fat oil of almonds; in the presence
of spirit of wine a turbid mixture is formed. By shaking nitrobenzol
containing spirit of wine with an equal volume of water in a graduated
cylinder, its volume decreases.
Oil of mirbane is much used for perfuming soaps, but even the finest
quality of it cannot replace oil of bitter almonds for fine soaps
and perfumery. Great care has to be exercised in storing, as well
as in working, nitrobenzol, it igniting very readily, and it is
also poisonous. Even the vapors, when inhaled for some time, may
produce symptoms of poisoning, which consist in the skin acquiring a
leaden color, and heavy feelings in the limbs with cold extremities,
especially the hands and feet.
FRUIT ETHERS. At the London Exhibition, in 1851, various products
called apple oil, pear oil, pine-apple oil, etc., were shown. They were
examined by A. W. Hofmann, and found to consist of solutions of certain
ethers in alcohol. Since then the manufacture has greatly increased and
large quantities are now brought into commerce under the name of _fruit
ethers_ or _fruit essences_.
Fruit ethers are fluids possessing an agreeable, refreshing odor
closely resembling that of some fruits. For this reason they are
used in confectionery, in the manufacture of liqueurs and also as
a substitute for volatile oils, in the manufacture of perfumery.
Chemically, fruit ethers are combinations of an organic acid--acetic,
butyric, valerianic, etc.--with a so-called alcohol radicle, such as
ethyl and amyl. The preparation of fruit ethers being connected with
many difficulties, is seldom attempted by perfumers, especially as
products of an excellent quality can at a low rate be procured from
chemical laboratories making a specialty of their manufacture. However,
for the sake of completeness, a brief description of the fabrication of
the principal ethers used in their preparation shall here be given.
_Acetic amyl ether_ or _amyl acetate_, C_{5}H_{11}O.C_{2}H_{3}O, is
prepared by mixing 1 part of amyl alcohol with 1 part of concentrated
sulphuric acid, and distilling the mixture with 2 parts of potassium
acetate. The distillate is washed with water, to which some carbonate
of soda has been added, and then rectified over magnesia. It forms a
colorless liquid of an agreeable fruity odor. It boils, according to
Kopp, at 280° F. and, at 59° F., its specific gravity is 0.8692.
For use in perfumery, the ether is best prepared, according to
Fehling's directions, by heating for some time at a temperature of 212°
F. 1 part of glacial acetic acid with ½ part of sulphuric acid and
one part of amyl alcohol. By then adding water the ether is separated.
By this process distillation is avoided.
_Acetic ethyl ether_ or _ethyl acetate_, C_{2}H_{3}O.O.C_{2}H_{5}.
Acetic ether is formed by the decomposition of sodium acetate by ethyl
sulphuric acid:--
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