A practical treatise on the manufacture of perfumery : $b comprising directions for making all kinds of perfumes, sachet powders, fumigating materials, dentrifices, cosmetics, etc., etc., with a full account of the volatile oils, balsams, resins, and other natural and artificial perfume-substances, including the manufacture of fruit ethers, and tests of their purityDeite, C. (Carl)
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A practical treatise on the manufacture of perfumery : $b comprising directions for making all kinds of perfumes, sachet powders, fumigating materials, dentrifices, cosmetics, etc., etc., with a full account of the volatile oils, balsams, resins, and other natural and artificial perfume-substances, including the manufacture of fruit ethers, and tests of their purity
Deite, C. (Carl)
Cosmetics; Perfumes; Perfumes industry
_Benzoic ether_ or _ethyl benzoate_, C_{7}H_{5}O.OC_{2}H_{5}, is most
readily prepared by mixing 4 parts of alcohol, 2 parts of crystallized
benzoic acid, and 1 part fuming hydrochloric acid, and for some time
heating the mixture in a flask. The benzoic acid is thereby gradually
and completely converted into ether. The fluid is mixed with water,
whereby the ether is completely separated. It is several times washed
with carbonate of soda solution, and, for the purpose of withdrawing
the last trace of free acid, distilled over lead oxide. It forms a
colorless oil of an aromatic odor, specific gravity 1.0502, and boils
at 412° F. In cold water it is insoluble. However, like all varieties
of ether, it dissolves readily in alcohol and ether.
_Butyric ethyl ether_ or _ethyl butyrate_, C_{4}H_{7}O.OC_{2}H_{5}. The
preparation of this ether must be preceded by that of butyric acid.
The latter is obtained, according to Bensch, by dissolving 6 lbs. of
cane sugar and 8 drachms of tartaric acid in 13 quarts of hot water,
allowing the liquid to stand a few days and then adding 7 ozs. of old
rotten cheese, which has been stirred up in 4 quarts of skimmed sour
milk and 3 lbs. of finely pulverized chalk. The mixture must be kept
at a uniform temperature of from 86° to 95° F. for some weeks, from
time to time mixing it by stirring, and replacing the water lost by
evaporation.
By the action of a ferment the sugar is first converted into lactic
acid. In 10 to 12 days the entire mass congeals to a paste of calcium
lactate. By now allowing fermentation to proceed without interruption,
it gradually enters another stage; gas bubbles consisting of carbonic
acid and hydrogen rise up, until in the course of 5 or 6 weeks the
process is finished. This is recognized by the fluid becoming quiet,
no more gas being evolved. The fluid then contains a solution of
calcium lactate, which is converted into the corresponding sodium salt
by the addition of 8 lbs. of crystallized soda. It is then filtered
and concentrated by evaporation to 5 quarts. By adding 5½ lbs. of
sulphuric acid, diluted with an equal volume of water, butyric acid is
separated as a dark-colored oily mass.
Public-domain text, read in full here on John Shaqi.
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